化学竞赛2009奥赛物化第一部分(932KB).pptVIP

At 600 K, CH3Cl(g) and H2O(g) react to form CH3OH, and then form (CH3)2O with a simultaneous equilibrium shown: (1) Starting with equal amount of CH3Cl and H2O, find the equilibrium amounts of all species. (2) Simultaneous Equilibria Suppose that a system initially contains 1 mole of CH3Cl(g) and H2O(g), x moles of HCl and y moles of (CH3)2O are formed at equilibrium. (1) (2) 1-x 1-x+y x-2y x x-2y y 1-x+y The equilibrium amounts of all species are (1) (2) 0.952 0.961 0.03 0.048 0.03 0.009 0.961 对于有离子参加的反应，规定H+ (aq,mH+ =1mol/kg)的摩尔生成吉布斯自由能 △f Gmθ(H+,aq,mH+ =1mol/kg)=0,由此可求出其他离子的标准摩尔吉布斯自由能。 化学