Electrochemistry：.ppt

AP CHM HW Read: Chapter 18 Review the Multiple-Choice Section of the Midterm. Electro-chemistry Determine Eo Zn(s) + 2 Ag+1(aq) 2 Ag(s) + Zn+2(aq) AP CHM HW Read: Chapter 18 Problems: 7 15a Page: 526 REDOX Shorthand Zn|Zn+2||Ag+1|Ag ox red Zn||Zn|Zn+2||Ag+1|Ag||Pt an ox red cat Drill: Determine Shorthand Rxn voltage when Cu+1 is reacts with solid potassium Voltaic Cell Problems Drill: What is the best reducing agent on the chart? A car battery has lead lead(IV)oxide electrodes in an acidified aqueous lead(II)sulfate solution. Using the book, determine the voltage that can be produced. Determine rxn, Eo, DGo, Keq for a voltaic cell with half-cells containing Ni(s)in NiCl2(aq) Sn(s)in SnCl2(aq). The test on electrochemistry will be on ____day. Electroplating Electro-purifying Electrolysis During electrolysis, oxidation degradation would occur at the anode while reduction electroplating would occur at the cathode Current Formula Current = charge/unit time Amps = coul/sec Amount (mass, volume, moles, etc) can be determined from the charge Calculate the mass of copper plated onto the cathode when a 9.65 mAmp current is applied to a solution of CuSO4 for 5.0 minutes. Current, Mass, Time Formula: nFm = MWIt Check HW Test Tuesday Balance the Rxn KMnO4 + HCl MnO2 + KClO2 A voltaic cell with a silver electrode in 0.10 M Ag+ a zinc electrode in 1.0 M Zn+2 at 27oC is allowed to react for 5.0 mins at 9.65 A.Calculate: Eo, E, DGo, mass increase of the cathode. Calculate the years required to plate 216 kg of silver onto the cathode when a 96.5 mAmp current is applied to a solution of AgNO3 Drill: Calculate the current required to purify 510 kg of aluminum oxide in 5.0 hours Determine all when a cell with a Cu electrode in CuCl2(aq) is connected to a cell with a Zn electrode in ZnBr2(aq) Determine all when a cell with a Fe electrode in FeCl3(aq) is connected to a cell with a Mn electrode in MnCl2(aq) Determine all