整筒聚碳硅烷原丝直径分布和缺陷分析-Core.PDFVIP

第 37 卷第 2 期 硅 酸 盐 学 报 Vol. 37 ，No. 2 2 0 0 9 年 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY February，2009 整筒聚碳硅烷原丝直径分布和缺陷分析 1,2 1 李思维 ，冯祖德 (1. 厦门大学材料学院，特种先进材料福建省重点实验室；2. 厦门大学化学化工学院，福建 厦门 361005) 摘 要：先驱体聚碳硅烷的纺丝工艺是制备高性能连续 SiC 纤维过程的关键环节，纺丝工艺决定了原丝的性能优劣，而纺丝工艺对聚碳硅烷原丝的损 伤程度也将决定最终的 SiC 纤维性能。为此，利用扫描电子显微镜对整桶纺出原丝的直径、表面和截面缺陷进行了观察，利用统计方法对直径和缺陷 的分布进行了分析。研究发现：原丝平均直径从外层到内层大体呈减小的趋势，并且每层数值波动逐渐减小，靠近中间层的原丝直径与整体平均值最 为接近。表面划痕由外层到内层划痕逐渐减少。鼓泡在各层之间呈均匀分布。断面气孔主要集中在最外几层原丝中。根据统计结果得到了结构特征分 布模型，建立了评价整桶原丝性能优劣的有效方法。 关键词：聚碳硅烷纤维；统计方法；扫描电镜；直径；缺陷分布 中图分类号：TQ174 ；O482.3 文献标志码：A 文章编号：0454–5648(2009)02–176–05 STATISTICAL ANALYSIS OF THE DEFECT AND DIAMETER DISTRIBUTION OF POLYCARBOSILANE FIBER LI Siwei 1,2，FENG Zude1 (1. Fujian Key Laboratory of Advanced Materials, College of Materials; 2. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China) Abstract: Continuous SiC fiber with high tensile strength and high modulus can be produced by the polymer precursor-derived method, which usually involves the synthesis of polycarbosilane (PCS), melt-spinning, air-curing and pyrolysis. The spinning is the key process that can determine the defects of PCS fiber and the properties of the SiC fiber. In order to study the performance of the PCS fiber, scanning electron microscopy was used to observe the fiber defects, and a statistical method was used to explore the defect distribution. The results show that the mean value of the PCS diameter decreases from the outer layer to the inner layer, and the number of surface scra