柴油加氢装置低分油换热器腐蚀泄漏分析.pdf

第29 卷 第6 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 29 No. 6 2017 年11 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Nov. 2017 柴油加氢装置低分油换热器腐蚀泄漏分析 马红杰 中国石油独山子石化分公司研究院 独山子 833699 摘要 催焦化柴油加氢装置反应系统E-206 低分油换热器管束发生腐蚀泄漏，其腐蚀产物能谱分析、X 射线衍 射分析结果表明，腐蚀产物主要为FeS ，腐蚀类型为湿H S 腐蚀。从影响管束腐蚀的工艺操作、管束设计及结 2 垢、温度、材质等因素进行了分析，结果表明管束腐蚀泄漏的根本原因是防冲板设计存在缺陷，使低分油流动 减缓，H S 腐蚀介质在此处积聚、浓缩，导致防冲板处管束遭受严重的湿H S 腐蚀而穿孔泄漏。此外，换热器壳 2 2 程温度的大幅升高增加了低分油中H S 腐蚀介质的反应活性，加速了腐蚀的发展。最后，针对该换热器管束的 2 腐蚀原因，提出了改造防冲板结构的防护建议。 关键词 柴油加氢 装置 低分油 换热器 腐蚀 中图分类号 TG 174 文章编号 1002-6495(2017)06-0687-04 Analysis on Corrosion Induced Leakage of Low Oil Heat Exchanger in Diesel Hydrogenation Unit MA Hongjie Research Institute of Dushanzi Petrochemical Company, Dushanzi 833699, China Correspondent: MA Hongjie, E-mail: yjy_mhj@ Manuscript received 2017-01-18, in revised form 2017-03-01 ABSTRACT An analysis on corrosion induced leakage of low oil heat exchanger in reaction system of hydrogenation unit for coker diesel and catalytic diesel was conducted by means of visual inspection, SEM with EDS and XRD. Results indicated that the corrosion products was ferrous sulfide，and the corro- sion type was wet hydrogen sulfide corrosion. The primary cause was that there existed deficiencies in the design of the impingement plate of tube bundle ，in this case low oil flowing slowly and hydrogen sul-