铁氧化物对有机磷的吸附特征及影响因素研究-环境科学与工程专业论文.docx

内蒙古大学硕士学位论文3．研究了不同pH(4～10)及温度(15。C、25。C、35。C)条件下铁氧化物 对OP。／Pi的吸附特征。结果表明：随着体系pH的增大，磷化合物在铁矿上的 吸附量减少；随着体系温度的提高，OP。／Pi在铁氧化物上的吸附量增加，表明 其在矿物上的吸附反应是吸热、自发的。4．LMWOAs对OP。／Pi在矿物表面的吸附有抑制作用。LMWOAs对OP。／ Pi在两种矿物上吸附率的影响大小顺序为：柠檬酸苹果酸草酸，且两种 矿物相比，LMWOAs对赤铁矿吸附OP。／Pi的抑制作用要大于针铁矿。关键词：铁氧化物；有机磷；吸附；环境因子万方数据内蒙吉大学硕士学位论文THE CHARACTERISTICS AND IMPACT王ACTORSOF ORGANIC PHOSPHORUS ADSORPTION ON IRON OⅪDESAB STRACTOrganic Phosphorus(OPs)constitutes large fraction of the total P pool and they can be utilized by primary producers．The interaction of OPs with iron oxides is important in controlling the mobility,transformation and bioavailability ofphosphorus in the environment．Three OPs，adenosine monophosphate(aMP,C loHl4N507P)， adenosine triphosphate(ATP,CIoHl4N5013P3)，and Glucose 6-phosphate(G6P, C6H1309P)，which characterized as different chemical structure and molecular sizes，and KH2P04(Pi)were used as adsorbates to investigate the kinetics and isothermadsorption characteristics on the hematite and goethite．In addition，we investigated the effect of environment factors such as pH，temperature and LMWOAs(oxalate，malate and citrate)on the adsorption process of OPs on both iron oxides．Meanwhile，the techniques of powder X-ray diffraction(XRD)，scanning electron microscopy(SEM)and the BET surface area analyzer were also used to explore and analyze the adsorption mechanisms ofOPs on iron oxides．This work is helpful to provide supporting evidenceIII万方数据内蒙古大学硕士学位论文to understand the interface processes of OPs on iron oxides．The main conclusions are as follows：1．The results showed that all curves of sorption kinetics presented similar characteristics，showing a fast adsorption and then followed by a slower process．Thesurface speciation of the P compounds on goethite are dominated by bidentatecomplexes，there may be coexistence of bidentate complex and three-dimensional precipitate at hematite surface．On each mineral，the order of the adsorption density and initial sorption rate for P compounds are listed as PiAMPG6PA