新型杂芴类有机光电材料的合成、表征及其应用-光学专业论文.docx

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2018-05-05 发布于上海
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新型杂芴类有机光电材料的合成、表征及其应用-光学专业论文.docx

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新型杂芴类有机光电材料的合成、表征及其应用-光学专业论文

AbstractAgreatdealofattentionhasbeenfocusedontheelectroluminescentmaterialsduetotheirgreatpotentialsin organiclight-emittingdiodes(OLEDs).Poly?uorene(PFs)areinvestigatedasblue-light-emittingmaterialsin OLEDsbecauseoftheirhighphotoluminescenceyields,highholemobility,goodphotostabilityandthermal stability,andtheemissionofbluelight.However,agreenemissionbandaround535nmand?uorescence self-quenchingareoftenobserved,whichmaybeconsideredtoberesultfromtheexcimersand9carbonatom’s oxidationintofluorenonewhichcanresultincolorunstablityandshortdevicelife-time.Theexcimersareakind ofexcited-statecomplexsformedbytheinteractionofanexcitedchromophorewithadissociativeground-state chromophore.Theincorporationofheteroatomsintoconjugatedsystemsisaneffectivemethodtomodifythe propertiesoforganicoptoelectronicmaterials.Heteroatomnotonlypossessesorbitsforσ*/d-πinteraction,but alsoallowschemicalmodificationsindiversewaystotunethepropertieseffectively.Duetothediversified chargeofdifferentposition,themodificationbetweenthemcauseenormousdiversity,suchaseffecttive conjugationlength,molecularconfiguration,molecularorbitalenergyandcrystalstructure.Forinstance, 1,8-functionalizedheterofluorenespossessuniquerigidand spatialtwistwarpstructurewhichfacilitatethe reductionofintermolecularπ–πstackingandenergylevelofthelowestunoccupiedmolecularorbital(LUMO). Introducingasmallamountoflow-band-gapchromophores,suchasbenzene,anthraceneandperylene,intothe backboneofPFisalsoaneffectivemethodtosolvetheproblemofpoorspectralstabilityofPFsandthismethod cansuppresstheexcimeremission,enhancethelength effectandthe qualityofthespectrumduetothethespecial structureofspacetorsionaltension.Basedonreformingthedrawbackoffluorene-basedmaterials,threeseriesof compoundsincludingfluorenesweredesignedandsynthesized,includingheterofluorenesandaromaticring conjugatedderivedmaterials.Thesematerialseffectivelyenhancetheshortcomingsoffluorenematerialsand improve the colorpurityofthe spectrum.Anewkindof1,8-functionalizedheterofluorenes