煤粉炉联产水泥熟料Q相矿物形成机制究.pdf

文章编号：1000-2367(2007)03-0103-05 煤粉炉联产水泥熟料Q相矿物形成机制0t：究 焦有宙1，王学涛2，徐广印1，张全国1 (1．河南农业大学机电工程学院，郑州450002;2．河南科技大学车辆与动力工程学院，河南洛阳 471003) 摘 要：选用分析纯CaO、SiO2、Al2O3和MgO为实验原料，首先在实验室高温电阻炉炉内开展了单矿物 2CaO·A12O3·SiO2转变为Q相矿物的反应机制实验研究．对获得的熟料样品分别进行XRD、SEM和EDs图谱分 析，实验结果表明单矿物2CaO·Al2O3·SiO3能与适量的CaO,MgO反应生成具有良好水化活性的Q相矿物．选取 低硫充州煤和高硫长广煤为实验煤种，在两段多相反应实验台上进行联产水泥熟料过程Q相矿物的生成实验，对所 得熟料进行矿物组成x射线衍射分析，结果表明低硫兖州煤和高硫长广煤联产水泥熟料，当混合煤粉中添加适量的 CaO、MgO时，联产熟料中有Q相矿物的生成，联产过程中Q相矿物的生成机制与单矿物2CaO·Al2O3·SiO2转化 为Q相矿物的反应机制相一致． 关键词：煤粉炉；Q相；联产：水泥熟料；形成机制 中图分类号：X773 文献标识码：A FormationMechanismofQ-phaseofCementClinkerCogeneration inPulverizedCoalCombustionBoilers J1AOYou-zhou1.WANGXue-tao2,XUGuang-yin1,ZHANGQuan-guo1 (1.CollegeofMechanicalandElectricalEngineering,HenanAgriculturalUniversity,Zhengzhou450002,China; 2.CollegeofVehicleandPowerEngineering,HenanUniversityofScienceandTechnology,Luoyang471003,China) Abstract:AnalyticalpureCaO,SiO2,Al2O3andMgOwereselectedasexperimentalmaterialsandexperimentsoftrans- formofpuremineralof2CaO ·Al2O3 ·SiO2intoQphasewereconductedonhigh-temperaturebox-typeresistancefurnace. ThecollecledclinkersampleswereanalyzedbyXRD,SEMandEDS,respectively.Theresultsshowedthatpure2CaO ·Al2O3 ·SiO2withsutiablecontentCaOandMgOcouldproduceQphaseofbetterhydrationperformance.Low-sulphurYanzhoucoal andhigh-sulphurChangguangcoalwereselectedasexperimentalcoals,experimentsofformationofQphaseintheprocessof cementclinkercogenerationwereperformedontwo-stagepolyphasereactionsetup.Thecollectedclinkersamplesweremeas- uredbyXRD.TheresultsshowedwhencoalpowderweremixedwithcertaincontentCaOandMgO,Qphasemineralappeared incogenerationcementclinker.TheformationmechanismofQphaseintheprocessofcementcogenerationaccordedwiththat oftransformofpure2CaO ·Al2O3 ·SiO2intoQphase. Keywords:pulverizedcoalcombustionboilers;Quaternaryphase;co-generation;cementclinker;formationmechanism