染料敏化太阳电池用聚苯胺对电极制备.pdfVIP

In Situ Oxidative Polymerization of Polyaniline Counter Electrode on ITO Conductive Glass Substrate Qi Qin, Jie Tao, Yan Yang, Xiang Dong College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, People’s Republic of China Polyaniline (PANI) electrode was synthesized on a con- (PANI) is one of the most potential conducting polymers ducting indium tin oxide glass by in situ oxidative poly- as counter electrodes due to its easy synthesis, high con- merization to construct a low production cost counter ductivity, and unique redox properties [7–10]. Among the electrode of dye-sensitized solar cell (DSSC). The scanning electron microscopy image showed that PANI previous research, it was reported that PANI was depos- electrode was a porous state with the particles diame- ited as a thin layer on various materials, [11] like glass, ter in 20–30 nm. The cyclic voltammogram measure- [12–15] metals, [16] as well as on polymeric supports ment revealed that PANI electrode had smaller charge [17–22]. The coating of various materials with a layer of transfer resistance and higher electrocatalytic activity conductive polymer is achieved by using several methods, 2 for I/I redox reaction. The Brunauer–Emmett–Teller 3 (BET) surface area of PANI was high to 53.114 m2/g, such as the spreading of a solution of conductive polymer and the high surface area of PANI electrode benefited on the surface of the material followed by the evaporation for the absorption of electrolyte. Finally, we compared of the solvent, [23] the electropolymerization of the the photoelectric p