almg金属间化合物对铝镁系牺牲阳极材料电化学性能的影响word格式论文.docx

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almg金属间化合物对铝镁系牺牲阳极材料电化学性能的影响word格式论文.docx

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almg金属间化合物对铝镁系牺牲阳极材料电化学性能的影响word格式论文

EffectofIntermetallics PhaseonElectrochemicalPerformanceofAI-MgAlloysforSacrificialAnodeSpecialty: MaterialProcessingEngineeringName: Wu TongInstructor: LiuChang-ruiABSTRACTCathodicprotectionbysacrificialanodesisoneoftheimportantmethodsforprotectingmetalmaterials.Thecommonanodematerialsincludezinc anodes，magnesiwnanodesandaluminwnanodes.Because ofAlwninwnalloyssuperiority，such臼high-energycapability(3.6由nesofzinc，1.35timesofmagnesiw啡，1ightweigh飞longlife，andlowcostcomparedwithmagnesiumandzincalloys.Aluminumalloyshavebecomepopul缸asgalvanicanodesforcathodicprotection.Butcommerciallypurealuminwne对对bitsarelativelynoblepotentialincorrosiveenvironrnentduetoanimperviousAl203filmonthesurface.Itisnotsuitableforsacrificialanode.Magnesiumalloyshavehighpotentialappliedtoironandsteel.Butitisnotsuitable岛rsacrificialanodetoo，becauseofthelowcurrentefficiencyandhighcorrosionrate.Thew町toimprovetheperformanceoftheanodesisalloyedwithotherelements.Tobaseonthealloyph臼eelectrochemis位ytheorem，也ispaperinvestigatedtheinfluence ofmagnesium contents onmicrostructure andelec仗。chemis位yproperties ofalloyanodes.Withthemagnesiumcontentsimprove，therearelargeareaintermetallicinalloy由uct山e.Inordertoimprovetheperformanceofalloyanodes，experimentalloyedwithZn，Mn，andRareEarthElementCe.Theopen potential，self-corrosionrate，pol彼泣硝onrate，electrochemicalprope此yandcorrosionmo甲hologywerestudied.Themainconclusionswereasfollowing:Whenthecontentofmagnesiumincreasedto10percent，largeareaintermetallicphaseMgsA18werebeformedinalloysmicrostructure.Experimentalresultsindicated也atithadanactivatedeffectonaluminwnalloyanodes.Withtheincreaseofmagnesiwnquantities，theopenpotentialwasreduce，andthepolarizationratewasdecreasedalso.Whenthecontentofmagnesiumwasincreasedto30%，theopenpotentialofAI-Mganodeswasreducedto-1.132Vin3.5%NaClsolution.However，thedissolutionofalloyedanodeswithmorethan20% quantitiesofmagnesiumwasunsymmetrical.Whenthecontentofmagnesiurnincreasedto60percent，theintermetallicphaseMg17Al12werebeformedinalloysmicros