alznfebi四元系相关相平衡的分析word格式论文.docx

AbstractHot-dipgalvanizingisaneffectiveandwidelyusedtechnologytoprotectsteel againstcorrosion.However,thehot-dipproductsaremademoredemandswiththe industrialdevelopment,suchassuperiorcorrosionresistance.TheAl-Znalloycoating exhibitingexcellentperformancebecomesoneofhottopicsofthehot-dip,inwhich 55wt.%Al-Zncoatingdevelopsrapidlybecauseofcomprehensivecharacteristics,but therearesomeproblemswhichareexcessivethicknessofcoatingcausingpoor formabilityandovermuchdrossatcontinuoushot-dipprocessincreasingcost.The additionofBi,Si,REetal.alloyelementstozincbathinhot-dipgalvanizingisa commonmethodbychangingthetypeandformingorderoftheintermetallic compoundstoimprovecoatingqualityorchangethetypeofthedross.Thefocusin theworkistheeffectofBionthemorphologyandthedrossin55wt.%Al-Znbath, whichisrelatedtothereactionbetweenAl,Zn,BiandFe.Inthepresentwork,the relatedphaseequilibriaoftheAl-Zn-Fe-Biquaternarysystemisdetermined experimentallytoprovidetheoreticalbasisforabetterunderstandingthereaction betweenFeand 55wt.%Al-Zn bath containingBi.PhaseequilibriaoftheZn-Fe-Bi,Al-Zn-Bi,fixed75at.%Aland50at.%Zn sectionsintheAl-Zn-Fe-Biisothermaltetrahedronat600℃ weredeterminedbyequilibratedalloysmethodcombinedscanningelectronmicroscopy(SEM)coupled withenergydispersiveX-rayspectroscopy(EDS)andX-raypowderdiffraction (XRD).Thefollowingresultareobtained,i.e.,(1)TheLphaseisinequilibriumwithδ,Γandα-FephaseintheZn-Fe-Biternarysystemat600℃,respectively.Twothree-phaseregionsL+α-Fe+ΓandL+Γ+δhavebeenidentified,andnonew ternaryphaseisfound.Biisalmostinsolublein δ, Γandα-Fe,andthesolubilityofFe intheliquidphaseislimitedbecauseoftheexistenceofBiinliquidphase.(2)One three-phaseregionL1 +L2+(Al)hasbeenconfirmedinAl-Zn-Biternarysystemat600℃,andtheliquidmiscibilitygapregionislarge.(3)Onefour-phaseregionL1+L2+FeAl3+(Al)hasbeenidentifiedinfixed75at.%AlsectionoftheAl-Zn-Fe-Bi isothermaltetrahedronat600℃.(4)Fourfour-phaseregionshavebeenconfirmedin fixed50at.%ZnsectionoftheAl-Zn-Fe-Biisothermaltetrahedronat600℃,namely L1+L