基于传热窄点的热泵用hfc125hcs混合工质优选及其系统特性研究-research on high quality selection and system characteristics of hfc 125 hcs hybrid heat pump based on heat transfer pinch points.docx

OPTIMAL SELECTION OF HFC125/HCs REFRIGERANT MIXTURES FOR HEAT PUMPAPPLICATIONS AND THEIR SYSTEMCHARACTERISTICSBASEDONPINCHPOINT?ABSTRACTTherefrigerantmixturesprovideanimportantdirectioninselectingnew environment-friendlyalternativetomatchthedesirablepropertieswiththeexisting halogenatedrefrigerantsor futureuse inthe newdevices, inwhich, HFCsrefrigerantswithzeroODPcombinedwithHCsrefrigerantswithzeroODPandlowerGWPareofimportantvalueinthefieldsofapplication.Inthepresentwork,aimingatheatpumpsystemsusingHFC125/HCsbinaryrefrigerantmixtures,thebehaviorofthestructuretypeoftheheatpumpusingsuchrefrigerantblends,optimalcompositionsofthemixturesandheattransfermatchingbetweensecondaryfluidandrefrigerantarestudiedtheoreticallyandexperimentally,whichcanbetakenasreferencesforlarge-scaleapplicationsoftherefrigerantblendsandsystemdesign infuture. Main conclusions are summarizedas follows:1）SelectionoftherefrigerantmixturesBasedonflameretardantandexcellentthermodynamicproperties, HFC125 refrigerantisselectedfromHFCsasbasiccomponent,andcombinedwithHC290, HC600,HC600aandHC1270,respectively.Itisfoundthat,bymixing,theGWPoftheHFC125isdecreasedeffectively,andtheflammabilityoftheHCsisinhibitedsignificantly, whichwillbeformedpromisingalternativerefrigerantsforheatpumps.2）DterminationoftheoptimalcompositonoftherefrigerantmixturesAthermodynamicmodelispresentedbasedonthepinchpointofheattransferfluids,andtheeffectsofmassfractionofmixturesontheheatpumpcycleperformanceare?TheprojectisfinanciallysupportedbyNationalNatureScienceFoundationofChina(NoIIIinvestigated.Undergivenconditions,comparedwithHCFC22,theresultsshowthattheCOPsoftherefrigerantmixturesHFC125/HC600andHFC125/HC600aarehigheratHFC125concentration6-66%and13-55%,respectively,andcompared with HFC134a,thedominantcompositionspanare10-46%,0-75%,5-68%and0-35%forrefrigerant mixturesHFC125/HC290,HFC125/HC600,HFC125/HC600aandHFC125/HC1270,respectively.Andatthesametime,thevariationoftheperformanceparameterswithmassfractionof HFC125exh