材料化学考古题.pdfVIP

1. 形成電雙層，可控制電子轉移交換進程的速率，進而影響粒子的穩定性 absorbed layer + diffuse layer Factors that affect the electrical double around an nano-sized sphere A. Size B. Temperature, dielectric constant and ionic strength of the medium 2. 位能變低 Ex. The congulation of Au colloidal particles ─The addition of pyridine to a gold sol leads to the colloidal particles to aggregate into strings as a result of the surface charge being reduced by the displacement of absorbed anions by a more strongly binding neutral adsorbate. 3. 位能變低 4.讓金屬的帶負電更大者會形成藍位移-答案如同他寫的 位在第一章後面 5. Steric stabilization (entropic effect and osmotic effect) ─The absorption of large molecules (polymers or surfactants) at the surface of particles SDS (sodium dodecyl sulfate, NaC12 H25 SO4 ) 6. Characterize the oxidation state of metal with XPS (X-ray photoelectron spectroscopy) + EDAX(EDS) 7. 鑑定結晶結構 transmission (TEM) =determination of the average diameter of nano-sized particles in XRD 8. 鑑定表面結構 SEM(運用secondary electrons)=three-dimensional shape 9. SERS surface enhanced raman spectroscopy =Metal carbonyl chemistry and using CO as a probe for surface structure 10. 13. 17. A.SAM B.DL C.The Organic Light-Emitting Diodes (OLED) ─Efficient organic thin-film electroluminescence forms the basis of a new generation of flat-panel display technology. ‧Methods of Production A. Laser Ablation Method B. Photolysis and Radiolysis C. Metal Vapor Synthesis Method D. Chemical Reduction Method E. Electrochemical Reduction Method Plasma: a kind of material containing both equal concentration of cations and anions and at least one of these ions are movable (e.g. molten salts, metals) 反應的是物質表面電荷的狀態 會吸收特定波長而震盪 當光線射到微小的粒子時，光會由粒子向四面八方漫射出來，稱為散射。散 射分為瑞立散射（Rayleigh Scattering ）及米氏散射（Mie Scattering ）兩種。 瑞立散射（Rayleigh Scattering ），為粒子較小的物體對光的散射作用，