锂电池正极材料lini13co13mn13o2的制备及改性分析-preparation and modification analysis of lini 13 co 13 mn 13 o 2 cathode material for lithium batteries.docx

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2018-05-29 发布于上海
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锂电池正极材料lini13co13mn13o2的制备及改性分析-preparation and modification analysis of lini 13 co 13 mn 13 o 2 cathode material for lithium batteries.docx

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锂电池正极材料lini13co13mn13o2的制备及改性分析-preparation and modification analysis of lini 13 co 13 mn 13 o 2 cathode material for lithium batteries

PreparationandModificationofLiNi1/3Co1/3Mn1/3O2asCathodeMaterialsforLithiumBatteriesAbstractBasedontheresearchanddevelopmentindetailonlithium-ionbatteriesandtheiranodeandcathodematerials,layeredLiNi1/3Mn1/3Co1/3O2wasselectedastheresearchobject,anditspreparationandmodificationwerestudiedinthisthesis.Ni1/3Co1/3Mn1/3CO3predecessorwaspreparedbyusingcarbonatecoprecipitationmethod.Weanalyzedfactorsofammoniaconcentration,reactiontime,mixingspeed,Ni-Co-Mnmetaltotalconcentration,high-pressureconditionofkettlehandledweretoinfluencetheimage,structureandelectrochemicalperformanceofpredecessorintheprocessofpreparation.Theresultsshowedthat:ammoniaconcentrationwas1.5mol/L,metalconcentrationwas1mol/L,responsewith200RPMfor10h,predecessortapdensitywashigherthanothersonthiscondition,weadoptedcontrapositiveanalysisanddiscoveredthattheprofileofmaterialwastreatedwithhigh-pressureconditionwasbetter,appearanceofthesamplepresentorbicular,graindiameterwasabout700nm.LiNi1/3Mn1/3Co1/3O2waspreparedbymixedcalcinationofNi1/3Co1/3Mn1/3CO3andLi2CO3,WhenthemolratioofLiandNi+Co+Mnwas1.08，cat-ionmixingratioofLiNi1/3Mn1/3Co1/3O2waslower.TG/DTAanalysisshowsthatNi1/3Co1/3Mn1/3CO3andLi2CO3havebecomedonefleshat500℃,performanceofpreheatingsampleswerebetter.Weanalyzedfactorsofcalciningheat,calciningtimeandcalciningatmosphereweretoinfluencethephysicalpropertieandelectrochemicalperformanceofmaterial,Itturnedoutthatmaterialperformancewasbettercalcinedunder900℃for20h,encebetweenoxidationandreductionpeakswereless,itshowedthatthesamplehadexcellentelectrochemicalproperties.Modifiedtocarboncoatedproductwithpolyacrylamideascarbonsource,throughcomparingthephysicalappearanceandelectrochemicalperformanceofdifferentPAMandNi1/3Co1/3Mn1/3CO3mixtureratio,it’sdiscoveredthatPAM10wasthebestsample.XRDandSEManalysisshowthatcarboncoatingdidn’tchangeLiNi1/3Co1/3Mn1/3O2structure,carboncoatedsamplepresentbettercycleperformance,ElSshowsthatimpedanceofcarboncoatedsampledecreased.Keywords:Predecessor,Carbon-coating,LiNi1/3Co1/3Mn1/3O2,