锂离子电池高压正极材料lini0.5mn1.5o4的可控制备与性能研究-controllable preparation and performance study of lini 0.5 mn 1.5 o4 as high-voltage cathode material for lithium ion batteries.docxVIP

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2018-05-29 发布于上海
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锂离子电池高压正极材料lini0.5mn1.5o4的可控制备与性能研究-controllable preparation and performance study of lini 0.5 mn 1.5 o4 as high-voltage cathode material for lithium ion batteries.docx

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锂离子电池高压正极材料lini0.5mn1.5o4的可控制备与性能研究-controllable preparation and performance study of lini 0.5 mn 1.5 o4 as high-voltage cathode material for lithium ion batteries

AbstractSpinelcathodeLiNi0.5Mn1.5O4offerstheadvantagesofbothahighcapacityandoperatingvoltage.Theseattractivefeatureshavemadethismaterialatopchoiceforthenextgenerationofhigh-powerbatteries.TheinfluenceonshapeandpropertiesofdifferentpreparationmethodandconditionarestudiedtocontrolledsynthesisLiNi0.5Mn1.5O4andimproveitselectrochemicalperformance.Theinfluenceonethanol-assistedhydrothermalsynthesisofLiNi0.5Mn1.5O4ofdifferentpreparationconditionisstudied.ParticlesizedecreasewiththeincreaseofNH4HCO3.ThepreparedLiNi0.5Mn1.5O4hasbetterrateperformancewhenmoreNH4HCO3isadded.TheparticlesizesynthesizedwithlargestconcentrationofLi+issmallest.TheLiNi0.5Mn1.5O4hasbetterdischargecapacityandstabilitywhentheconcentrationofLi+is0.4molL-1.Withtheincreaseofcalcinationtemperature,particlesizeanddegreeofcrystallinityincrease,leadingtobettercyclingperformance.Thecomparisonofethanol-assistedhydrothermalmethod,precipitationmethodandhydrothermalmethodindicatesthattheethanol-assistedhydrothermalprocessdecreasesthesizeandaggregationdegreeofparticles,improvesthecrystallinityandmixesthereagentshomogeneously,leadingtolowimpurityandMn3+ionscontents.TheLiNi0.5Mn1.5O4materialsynthesizedbyethanol-assistedhydrothermalmethodexhibitsexcellentratecapabilitywithdischargecapacitiesof81.7mAhg-1atrate20C.What’smore,after1000cyclesat5Cdischargerate,itsdischargecapacityis102.1mAhg-1withcapacityretentionratioof88.1%..TheinfluenceonshapeofMnCO3ofdifferentpreparationconditionisstudied.Withtheincreaseofcalcinationtemperature,particlesizeanddegreeofcrystallinityincrease.Withtheincreaseofreactiontime,particlesizeanddegreeofcrystallinityincrease.Withtheincreaseofethanol,particlesizedecreaseanddegreeofcrystallinityincrease.SphericalandhollowLiNi0.5Mn1.5O4aresynthesizedbyprecursorswithdifferentshapes.ThesphericalLiNi0.5Mn1.5O4issynthesizedbyMnCO3sphere.Besides,MnCO3iscalcinedat350oCandtheouterlayeristransformedintoMnO2andMnCO3innercoreremineaftercalcination.TheMnO2outerlayerremainandMnCO3innercoreisdissolvedafteracidpick