高浓度co2气氛下no释放及火焰特性的动力学分析-kinetic analysis of no emission and flame characteristics in high concentration co2 atmosphere.docx

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2018-06-01 发布于上海
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高浓度co2气氛下no释放及火焰特性的动力学分析-kinetic analysis of no emission and flame characteristics in high concentration co2 atmosphere.docx

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高浓度co2气氛下no释放及火焰特性的动力学分析-kinetic analysis of no emission and flame characteristics in high concentration co2 atmosphere

AbstractOxy-fuelcombustionisoneoftheseveralpromisingnewtechnologieswhichcanrealizetheintegratedcontrolofCO2,SO2,NOXandotherpollutants.MoststudieshavefoundsignificantlylowerNOxemissionsandunstableignitioncombustioncharactersduringOxy-coalcombustion.WhenfuelsareburnedinthehighCO2concentrationenvironment,itsNOxgenerationandconversionprocesscombustioncharacteristicscanbeverydifferentfromconventionalair-firedcombustion.SuchchangesimplythatthehighCO2concentrationatmospherehavephysicallyandchemicallyimpactsonthecombustionprocesses.Uptonow,detailedandquantitativeresearchesonthehighCO2concentrationatmosphere’seffectontheNOxandflamecharacteristicsarestilllimited,whilehighCO2concentrationschemicaleffectonNOxconversionhasnotbeenwellstudied.Inthispaper,NOxcombustionchemistryunderO2/CO2atmosphereaswellasairatmospherewasstudiedusingdetailedkineticmodel.Asuitablereactionmechanismwaschosenbasedonthecomparisonbetweenthecalculationresultandtheexperimentaldata.Theinfluenceofvariousparameters(atmosphere,temperature,pressure,CO2concentration,O2concentration)onNOxconversionwasalsoinvestigated.ComparedwithO2/CO2atmosphere,airatmosphereisfavoredtoachievelowerNOemissionatfuel-richcondition.Atfuel-leancondition,thereisnotmuchdifferenceofNOemissionbetweendifferentatmospheres,andO2/CO2atmospherehelpstocontrolNOemissionalittlebit.Andthetrendisreversedinlowertemperaturewindowfrom1250Kto1450K,onlyatfuel-richcondition;highertemperaturescauselowerNOemissionsunderbothatmospheres.ItcanbeconcludedthathighCO2concentrationatmospheredoesaffecttheNOpollutantemissionbehaviour.ThechemicaleffectsofhighCO2concentrationonNOformationanddestructionprocesswasstudied.ThedominantreactionstepscontributiontoproductionanddestructionofNOaswellasthemostimportantreactionsforNOreductionunderdifferentatmosphereswerediscussed.Onthebasisofinvestigationsthroughelementarychemicalreactions,itcanbeconcludedthathighCO2concentrationplayapronouncedroleonNOxconversionprocess.ThisworkissupportedbyNationalScienceFoundationofChina(Grant