红外光谱的样品制备（Sample preparation of infrared spectrum）.docVIP

红外光谱的样品制备（Sample preparation of infrared spectrum） Part one liquid The liquid sample is prepared by applying a small amount of sample to two pieces of infrared transparent windows (KBr, NaCl, etc.). The pieces of the window are extruded to form a thin layer of sample, and the composition of the sample determines which window to choose. For anhydrous samples, the window material is KBr. For aqueous samples, KRS-5 is suitable. solid Solid samples challenge scientists. The melting point of the sample indicates which technique should be considered first. For melting point less than 72. The sample of C is dissolved in proper solvent and the film is first considered on the KBr window. If it is not successful because of poor baseline or poor solubility, it may be possible to fuse the film into two KBr windows. If this doesnt work, the sample can be KBr pressed. For melting points higher than 72. The preferred technique for C samples is KBr tabletting. For polymer samples, the film forming method is preferred, followed by hot-melt and tabletting methods. For samples of unknown melting point, the determination of crystallinity will indicate which technique will be successful. The sample with high crystallinity is better by KBr pressing method, and better spectrum can be obtained for low crystallinity sample film and hot melt. Second part Liquid sample There are many ways to analyze liquid samples. In this paper, we mainly discuss the sample preparation method and some related potential problems. Pure sample technology The most commonly used method for the analysis of liquid samples is a drop of liquid in the middle, two salt tablet process is as follows: one drop of sample drops on salt tablet right, after a few seconds, another piece of salt tablets combined, this liquid is sandwiched between two pieces of salt tablets into thin film. Of course, the choice of salt tablets should be compatible with the analytical liquid sample. No water samples by KBr (32 * 5mm) salt tablets