岩石中硼提取分离及同位素组成测定.docVIP

岩石中硼提取分离及同位素组成测定 　　摘要:介绍了一种用 Na2CO3 + K2CO3 混合熔剂对岩石样品进行分解 ,用硼特效树脂和阴、阳混合离子交换树脂相结合进行岩石样品中硼的纯化分离的方法。采用该方法从岩石样品中提取、分离出来的硼能满足硼同位素质谱法测定的需要 ,不产生硼同位素分馏 ,硼同位素测定精度大多优于 0. 05 %。 　　 Abstract : A method for isotopic determination of boron in rock samples was developed in this study. The rocksamples were decomposed with the mixture of Na2CO3 and K2CO3 . Boron in sample was then purified by ionexchange with Amberlite IRA 743 resin and the mixture of cation2exchange resin (H+form) and anion2ex2change resin (ion2exchanger Ⅱ, HCO-3 form) . The sample pret reatment method can meet the requirement ofboron isot