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sapo5分子筛及膜的合成与应用-synthesis and application of sapo 5 molecular sieve and membrane
ABSTRACTDifferent morphologies SAPO-5 molecular sieve membranes were synthesized on the α-Al2O3 substrate by using in situ crystallization by conventional heating. Changing the conditions of synthesization, such as the ratio of H2O/Al2O3, crystallization time, chitosan layer, their influence on the purity, morphology and density was investigated. The SAPO-5 membranes were characterized and analysis by SEM, XRD. The dense and prefered c-oriented SAPO-5 membranes were synthesized on the α-Al2O3 substrate by spinning chitosan layer. Furthermore, different metal elements (Fe, Co, Ni and Mn) can be introduced into the framework of AFI type crystals under this synthesis condition. But the morphology and purity of crytals have a great of difference according to different kinds of metals.The Cr-AFI crytals and membranes were synthesized with polyethylene glycol (pEG) as a cosolvent and characterized by SEM, XRD, FT-IR, UV-vis. Changing the reaction conditions, such as heating mode, the volume ratio of pEG/H2O, the molecular ratio of Cr/Al2O3, H2O/Al2O3 and Si/Al2O3, their morphology, crystallinity and purity of molecular sieves and membranes was investigated. It is very difficult to synthesize the CrAPSO-5 membrane by in situ hydrothermal on α-Al2O3 substrate. To find the appropriate coating is the key to solve the problem. Howerver, it is easier to synthesize a dense and thin CrAPSO-5 membrane with prefered c-orientation by secondary growth. FT-IR spectroscopy proves that it effectively to remove the template agent located in molecular sieve membrane using high temperaturecalcination. Through UV-vis, it can be conclusion that Cr3+ had entered theframework of crytals and membranes of AFI type and the ligand environment of Cr element had changed after calcination, acidity and active center of zeolite crystals were increased.The activity of these crystals and membranes were evaluated in the reaction of cyclohexane oxidation, the conversion of cyclohexane i
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