新型环三磷腈单体的合成及其共聚物发光材料的性能分析-synthesis of novel cyclotriphosphazene monomer and analysis of properties of copolymer luminescent materials.docx

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2018-06-03 发布于上海
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新型环三磷腈单体的合成及其共聚物发光材料的性能分析-synthesis of novel cyclotriphosphazene monomer and analysis of properties of copolymer luminescent materials.docx

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新型环三磷腈单体的合成及其共聚物发光材料的性能分析-synthesis of novel cyclotriphosphazene monomer and analysis of properties of copolymer luminescent materials

AbstractCyclotriphosphazeneisaninterestingnovelinorganicmaterialthatbearscharacteristicsofthermalandchemicalstabilityandsuch,itsuniquemolecularstructureopensmanypossibilitiesforsyntheticchemistry,anditsoutersubstituentgroupscanbereadilymodifiedondemand,henceanimportantsyntheticintermediateandhasattractedincreasingattentioninrecentyears.8-hydroxyquinoline(8HQ)anditsmetalcomplexisanoutstandingphoto-luminescence(PL)andelectroluminescent(EL)material,withitshighelectronmobilityandluminescentefficiency,ithasbecometheluminescentmaterialswithmostpotential.However,theconventional8-hydroxyquinolinematerialsuffersfromsolubilityandprocessability,anditsthermalstabilityandlifespanoftendoesnotmeettherequirementofthemostdemandinghigh-endapplications.Inrecentyears,muchefforthasbeendevotedintodevelopingnovel8-hydroxyquinolinematerialswithhighprocessibility,highstabilityandhighfluorescenceefficiency.Inthiswork,weintroducedamethacrylategroupontheouterringofcyclotriphosphazeneanddevelopednovelphosphazene-basedmonomer5,andintroducedamethacrylategroupon5-of8HQanddeveloped8HQ-basedmonomer8,andthetricoordinatedwithAl(III)toobtainmonomer13,thestructuresofthemonomerswerecharacterizedbyFTIR,1HNMR,13CNMR,31PNMR.Linearcopolymer10wasobtainedbythecopolymerizationofmonomer5andMMA,andlinearcopolymer11wasobtainedbythecopolymerizationofmonomer5and8,itscomplexpolymer12withAl(III),andthecrosslinkingpolymermembraneof14andtrifunctionalthiolvia‘ClickChemistry’.ThestructuresandpropertieswerecharacterizedbyFTIR,1HNMRandGPC,thefluorescencepropertiesof12werecharacterizedbyUV-Visandfluorescencespectra.ThethermalperformancewasmeasuredbyDSCandTG.Theresultsshowedthatpolymercomplex12possessfavorablefluorescenceproperties,themaxexcitewavelengthwaslocatedat390nm,thetypicalAl(8HQ)3excitewavelength.Thefluorescencequantumyieldcouldbeashighas6.7%indilutesolutions,buttheyielddecreasedwiththeincreasingof8HQmoiety.Andthepolymercomplex12showedfavorablethermalperformance.Keywords:Cyclotriphosphazene8-hydroxyquinolineCopolymer