基于芳香羧酸及含氮类配体构筑金属有机框架物-construction of metal organic frameworks based on aromatic carboxylic acids and nitrogen-containing ligands.docx

Themetal-organicframeworksconstructedbyaromaticcarboxylicacidandN-containingligandsAbstractMetal-OrganicFrameworks(MOFs)areatypeofcoordinationcomplexesconstructedthroughmetalionsandligands.Theyhaveextensiveapplicationprospect,gasabsorption,catalysis,opticalandmagneticmaterials.Scientistsschemeoutmanycompoundswithnovelstructureinrecentyears.Itisimportanttomasterthefactorsinfluencingthestructureofthecoordinationcomplex.Inthisthesis,onthebasisofsevencarboxylicacidandN-containingligands:2,4,6-trimethyl-1,3,5-benzenetricabonicacid,4,6-dimethyl-5-nitro-isophthalicacid,Bis(2-｛5-[(2-carboxyphenyl)sulfanyl-methyl]-2,4-dimethylbenzylsulfanyl｝-benzoato),1,2,2-trimethyl-1,3-cyclopentanedicarboxylicacid,2-tetrazole-1-methylenetetrazole-benzene,(2E)-2-[(2,3–dihydroxyphenyl)methylene]hydrazone,4,4’-bipyridyl,wesynthetized10novelcoordinationcomplexes:Cu(2,4,6-trimethyl-1,3,5-benzentricabonicacid,Cd(phen)(4,6-dimethyl-5-nitro-isophthalicacid),Zn(4,6-dimethyl-5-nitro-isophthalicacid)(pyridine),Co2(1,2,2-trimethyl-1,3-cyclopentanedicarboxylicacid)2(H2O)44,4’-bipyridyl,Co(Bis(2-｛5-[(2-carboxyphenyl)sulfanyl-methyl]-2,4-dimethylbenzylsulfanyl｝-benzoato))2(pyridine)2,Fe(Bis(2-｛5-[(2-carboxyphenyl)sulfanyl-methyl]-2,4-dimethylbenzylsulfanyl｝-benzoato))2(pyridine)2,Zn(2-tetrazole-1-methylenetetrazole-benzene)H2O,Cu3((2E)-2-[(2,3-dihydroxyphenyl)methylene]hydrazone)2(CH3OH)3,Cu2(4,4’-bipyridyl)2SO4.(H2O)8.Allcomplexeshavebeendeterminedbysingle-crystalX-raydiffraction.Complex1isthree-dimensionalcomplex;complex2istwo-dimensionalinterpenetratedlayers;complex3istwo-dimensionalcomplex;complex4istwo-dimensionalinterpenetratedcomplex;complex5and6issupramolecularcomplexes;complex7isthree-dimensionalcomplex;complex8iszero-dimensionalcomplex;complex9belongstoone-dimensionalchain.Thethermogravimetricanalysiswasdiscussed.Inconclusion,ourresearchworkwasfocusedonthecomplexwiththearomaticcarboxylateandN-containingligands.Theresultswouldbeinfavorofourfurtherwork.Keywords:CarboxylicacidandN-containingligand