基于芳香多酸及含氮多酸构筑的金属-有机框架物及性能分析-metal-organic framework based on aromatic polyacid and nitrogen-containing polyacid and its performance analysis.docx

Study on Synthesis and Properties of metal organic frameworks based on aromatic tetracarboxylic acid and nitrogen-containing aromatic dicarboxylic acidAbstractMetal-organic frameworks, also known as coordination polymers, are a type of self--assembly coordination compounds formed by organic ligands and metal ions. Due to the wide applications of coordination complexes in photoelectricity, magnetic material, redox catalysis, ion exchange, gas adsorption, separation and molecular recognition etc., much attention has been devoted to the design and synthesis of novel kinds of structural topologies and compounds with special properties.Aromatic carboxylic acid andnitrogen-containing aromatic carboxylic acid, that is, 2H-imidazole-4,5-dicarbonitrile, 5-(3-(tetrazo-5-yl)phenyl)isophthalic acid,1,1’,4’,1’’,-4’’, 1’’’-quterphenyl-3,4,3’’’,4’’’-tetracarboxlic acid, 4,4’-bis(imidazol-1-ylmethyl)-biphenyl, 4, 4’-bis(imidazolyl)biphenyl and benzimidazole ,were chosen as ligands or coligands to r eact with transition metal ions and rare-earth metal ions, and seventeen kinds of metal-organic frameworks with novel structures were obtained by the hydrothermal/solvother mal and the room temperature diffusion methods. The structures and thermal stabilizati ons of the coordination polymers were characterized by many kinds of analysis metho ds, such as X-ray single crystal diffraction, elementary analysis and thermal gravity an alysis.At the same time, the fluorescence and magnetic properties of the parts of metal-organic frameworks were characterized. The results are as follows:First, seventeen kinds of metal-organic frameworks with novel structures were obtained by the hydrothermal/solvothermal and the room temperature diffusion methods.Second, single crystal X-ray diffraction analysis shows;twelve metal-organic framew ors(1-10, 16and17) with 3D network structure; One metal-organic frameworks with 2D planestructure; One metal-organic frameworks with 1D cha