几种无机功能纳米材料的合成 组装及性质分析-synthesis, assembly and properties analysis of several inorganic functional nanomaterials.docxVIP

strong visible emission was also proposed that oxygen vacancies and surface defects play an important role in the visible emission based on the results of electron paramagnetic resonance (EPR) spectra and decay lifetime curve. ZnO nanoparticles with strong visible emission centred at 500 nm could also be obtained by changing the compositions of coordination polymers. This solid-state transformation method provides a new approach to synthesize stable ZnO nanoparticles with strong and tunable visible emission under a wide range of compositions of coordination polymers.3. Synthesis of indium oxide nanocrystals with the porous octahedral shape by solid-state transformation of In(III)-organic coordination polymersIndium oxide nanoparticles were synthesized by two steps. First, In(III)-organic coordination polymer particles with octahedral shape prepared, and then the coordination polymer particles transformed to indium oxide crystals with the morphology of porous octahedral by annealing the precursor at 550 oC . Sample was characterized by XRD, SEM, TEM, BET and UV-vis which has shown that the specific surface area is 25 m2 g-1 and the particles with a mean diameter of 15 nm composed the indium oxide nanocrystals with the morphology of porous octahedron. Controlling the morphology of precursor can control the shape and properties of metal oxide. Its potential application should to be further investigated.Key words: self-assembly at interface, metal oxide, nanowires, coordination polymer, optical properties中国科学技术大学学位论文原创性和授权使用声明本人声明所呈交的学位论文,是本人在导师指导下进行研究工作 所取得的成果。除已特别加以标注和致谢的地方外，论文中不包含任 何他人已经发表或撰写过的研究成果。与我一同工作的同志对本研究 所做的贡献均已在论文中作了明确的说明。本人授权中国科学技术大学拥有学位论文的部分使用权，即：学 校有权按有关规定向国家有关部门或机构送交论文的复印件和电子 版，允许论文被查阅和借阅，可以将学位论文编入有关数据库进行检 索，可以采用影印、缩印或扫描等复制手段保存、汇编学位论文。保密的学位论文在解密后也遵守此规定。作者签名： 年月日第一章绪论1.1研究背景美国著名化学家、诺贝尔奖获得者 R.B.Woodward 认为化学是在原有的自 然界旁边放了一个新的、人造的自然界，而纳米化学的出现无疑使得这个新的 自然界更加绚丽多彩[1]。纳米原本是一个长度单位。一个纳米为十亿分之一米，更直观来说，一张 纸的厚度大约是十万个纳米，一个金原子的直径大约是三分之一个纳米。纳米 科学是研究尺寸在接近 1-100 n