几种油田水用缓蚀剂的合成 评价及机理分析-synthesis, evaluation and mechanism analysis of several inhibitors for water use in oil fields.docxVIP

AbstractThree new 3,5 - dibromosalicylaldehyde Schiff base compounds（L1,L2,L3） and three new 2 - aminobenzimidazole Schiff base compounds（D1,D2,D3） havebeen synthesized and characterized by X-ray diffraction, ultraviolet-visible spectrophotometry (UV-vis), infrared spectroscopy (IR), fluorescence spectra, the thermogravimetry (TG/DTG) and nuclear magnetic resonance spectroscopy (H1─NMR) .The weight loss methods, electrochemical methods, scanning electron microscopy and X-ray photoelectron spectroscopy were performed to study the corrosion inhibition performance of six Schiff bases for carbon steel in oilfield water. The weight loss methods and polarization curves measurements show that six kinds of Schiff base corrosion inhibitors have excellent corrosion inhibition performance, and the inhibition efficiency of six corrosion inhibitors have reached 80% or more withthe concentration of 75mg / L. The order of inhibition capacity was: L2＞ L1＞ L3and D3＞ D2＞ D1, and all of them belong to mixed type corrosion inhibitor which mainly inhibit anode reaction. Electrochemical impedance show that the value of charge transfer resistance increased significantly after adding corrosion inhibitors,which indicate that corrosion inhibitors have great inhibitive properties for carbon steel. Scanning electron microscopy show that the corrosion degree of carbon steel surface decreased greatly after adding corrosion inhibitors. X-ray photoelectron spectroscopy indicate that the corrosion inhibitor molecules can pack together on carbon steel surface to form a dense monolayer.The molecular dynamics simulations software Materials Studio5.5 was performed to study the adsorption process of the corrosion inhibitor molecules on Fe(1 0 0) surface and the diffuseness process of corrosion medium particles in corrosion inhibitor film. The results show that corrosion inhibitor molecules could parallel adsorbed on Fe (1 0 0) surface with the manner of multi-center parallel adsorption. The adsorption