化学包覆法制备TiO__SiO_复合物.docVIP

------------------------------------------------------------------------------------------------ —————————————————————————————————————— 化学包覆法制备TiO_2_SiO_2复合物 第15卷第5期 Vol.15 No.5 粉末冶金材料科学与工程 2010年10月 Materials Science and Engineering of Powder Metallurgy Oct. 2010 化学包覆法制备TiO2/SiO2复合物 姚志通1, 2，夏枚生1，叶 瑛1 (1. 浙江大学 海洋科学与工程学系，杭州310028；2. 清华大学 环境科学与工程系，北京 100084) 摘 要：与TiO2光催化剂相比，以SiO2为载体或内核制备的TiO2/SiO2复合催化剂，其表面活性、光催化活性和热稳定性都更高。以粉煤灰为原料制备的沉淀SiO2为硅源，钛酸四丁酯为钛源，采用化学包覆法制备TiO2/SiO2复合物，采用扫描电镜(XRD)、红外光谱(FT-IR) 和差热分析(TG-DTA) 等测试手段对该复合物进行表征。FT-IR和TG-DTA分析证实，SiO2被TiO2有效包覆。复合物热稳定性较高，经700 ℃焙烧4 h后，SiO2仍为无定形，TiO2以锐钛矿相为主；在900 ℃焙烧后，TiO2大部分由锐钛矿相转变为金红石相。 关键词：二氧化钛；沉淀二氧化硅；化学包覆；粉煤灰 中图分类号：TQ 171.4 文献标识码：A 文章编号：1673-0224(2010)5-474-05 Preparation of TiO2/SiO2 composite by chemical coating method YAO Zhi-tong1, 2, XIA Mei-sheng1, YE Ying1 (1. Department of Ocean Science and Engineering, Zhejiang University, Hangzhou 310028, China; 2. Department of Environmental Science and Engineering , Tsinghua University, Beijing 100084, China ) Abstract: As compared to TiO2 photo-catalyst, the surface activity, photocatalytic activity and thermal stability of TiO2/SiO2 composite catalyst, which prepared using SiO2 as carrier or nuclear, are better. The precipitated silica was obtained from fly ash. The titania/silica (TiO2/SiO2) composite was prepared by chemical coating method using precipitated silica and tetrabutyl titanate as precursors. The composite was characterized by means of X-ray difractometry, FT-IR spectroscopy and TG-DTA analysis. It is confirmed that the silica is efficiently coated by titania through FT-IR spectroscopy and TG-DTA analysis. The TiO2/SiO2 composite possesses high thermal stability. The phase of silica remains amorphous and titania is anatase after the composite calcined at 700 ℃ for 4 h. While, titania transforms into rutile when calcined at 900 ℃.