Integrated Rate Law:采用综合评分法.ppt

  1. 1、本文档共17页,可阅读全部内容。
  2. 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
  3. 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载
  4. 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
查看更多
Integrated Rate Law:采用综合评分法

Integrated Rate Law Integrated Rate Law: Advantages of the Method of Initial Rate: Advantages of the Integrated Rate Method: Common Uses of the Method of Initial Rates: Common Uses of the Method of Integrated Rate Laws: Concentration of D over Time * A reaction is followed for an extended period of time. Method of Initial Rates A reaction is followed for only the first few moments of the reaction. 1. Useful when a reaction is reversible. The reverse reaction won’t significantly contribute to the first few moments of the reaction. 2. Useful for very fast or very slow reactions. 1. Useful for moderate length reaction. 2. Doesn’t require multiple experiments to determine the order of the reaction. 1. To determine the order of the reaction. 2. Find the rate constant, k . 1. To determine the order of the reaction. 2. Find the rate constant, k . 3. To determine the concentration at a certain time. 4. To determine at what time a certain concentration will be reached. This is the raw data collected during the experiment Start your analysis by graphing [D] v. Time The data do not form a straight line. The R2 value only has one “9”. This reaction is NOT zero order! R2= 0.9737 Next, convert your raw data to natural logs and graph ln[D] v. time R2 = 1.0 The data DO form a straight line. The R2 value is 1.0. This reaction is first order. Normally, when you get a straight line you stop making graphs. For teaching purposes, let’s go ahead and look at the third kind of graph: 1/[D] v. time *

您可能关注的文档

文档评论(0)

ctuorn0371 + 关注
实名认证
内容提供者

该用户很懒,什么也没介绍

1亿VIP精品文档

相关文档