稀土铕_镨掺杂钛酸锌红色荧光粉的制备及其发光性能研究_李梦婷.docVIP

------------------------------------------------------------------------------------------------ —————————————————————————————————————— 稀土铕_镨掺杂钛酸锌红色荧光粉的制备及其发光性能研究_李梦婷 稀土铕、镨掺杂钛酸锌红色荧光粉的制备及其发光性能研究 李梦婷1,2，焦宝祥2，杨润放2，游 璐2 （1.江苏大学，材料科学与工程学院，镇江 212013 2.盐城工学院 材料工程学院，盐城 224051） 摘 要：利用溶胶-凝胶法(sol-gel)分别制备了稀土铕掺杂钛酸锌和镨掺杂钛酸锌粉体，通过X射线衍射仪（XRD）、傅里叶变换红外光谱仪（FT-IR）、透射电子显微镜（TEM）以及荧光分光光度计（PL）对样品的结构、形貌及发光性能进行了表征。结果表明，Eu3+掺杂钛酸锌呈六方相偏钛酸锌，而Pr3+掺杂钛酸锌呈现六方相偏钛酸锌和立方相正钛酸锌。荧光分析表明，Eu3+浓度在0～3.0％研究范围内，其发光强度随Eu3+浓度的增加先增强后降低，最大发光强度为1.5％；Pr3+浓度在0～0.5％研究范围内，其发光强度随Pr3+浓度的增加先增强后降低，最大发光强度为0.3％，且Eu3+掺杂钛酸锌的红光发射强度远比Pr3+大。研究表明铕掺杂钛酸锌荧光粉可作为一种潜在的白光LED用红色荧光粉。 关键字：铕；镨；钛酸锌；发光 中图分类号：TN304.91 文献标识码:A 文章编号：1001-9642（2015）10-0023-06 DOI：10.16521/ki.issn.1001-9642.2015.10.005 Synthesis and Photoluminescence Properties of ZnTiO3∶RE (RE = Eu3+、Pr3+) Red Phosphors LI Mengting1,2, JIAO Baoxiang2, YANG Runfang2, YOU Lu2 (1.School of Materials Science and Engineering，Jiangsu University，Zhenjiang 212013，China； 2.School of Materials Engineering, Yancheng Institute of Technology，Yancheng 224051，China) Abstract：ZnTiO3∶Eu3+ and ZnTiO3∶Pr3+ phosphors were synthesized through sol-gel method. The synthesized powders was characterized by XRD, FT-IR, TEM and photoluminescence spectroscopy. The results showed that the ZnTiO3∶Eu3+ phosphors were hexagonal ZnTiO3 and ZnTiO3∶Pr3+ phosphors were hexagonal ZnTiO3 and cubic Zn2TiO4. The photoluminescence (PL) results indicated that 1.5% Eu3+ doped ZnTiO3 showed the strongest luminescent intensity with Eu3+ concentrations range from 0～3.0%. And 1.3% Pr3+ doped ZnTiO3 showed the strongest luminescent intensity with Pr3+ concentrations range from 0～0.5%. Moreover, the red luminescent intensity of Eu3+ ions was far stronger than that of Pr3+ ions. The luminescence properties suggested that ZnTiO3∶Eu3+ phosphors may be regarded as a potential red phosphor candidate for light emitting diodes (LEDs). Key wo