化学类专业论文：臭氧和过氧化氢协同电化学产生技术研究Cogeneration of ozone and hydrogen peroxide by electrochemical method.pdfVIP

中国科技论文在线 臭氧和过氧化氢协同电化学产生技术研究# 王云海，周喆，李国* （西安交通大学能源与动力工程学院环境工程系，西安 710049 ） 5 摘要：研究了用自制的 Ni-Sb-SnO2/Ti 作为阳极，空气扩散电极作为阴极电化学协同产生臭 氧和过氧化氢的技术。水在阳极区被氧化产生臭氧，氧气在阴极区被还原成过氧化氢。讨论 了电池电压及电解液配置对产生过氧化氢和臭氧的电流效率的影响，阴极基底对产生过氧化 氢电流效率的影响以及电解时间对产生臭氧和过氧化氢的电流效率的影响也进行了讨论。结 果发现产生过氧化氢和臭氧的电流效率最高分别达到 12.3%和 6.5% 。 10 关键词：环境工程；臭氧；过氧化氢；电化学；协同 中图分类号：TQ151 Cogeneration of ozone and hydrogen peroxide by electrochemical method 15 WANG Yun-Hai, ZHOU Zhe, LI Guo (Department of Environmental Engineering, School of Energy and Power Engineering, Xian Jiaotong University, Xian 710049) Abstract: By using lab-made Ni-Sb-SnO2/Ti as anode and gas diffusion electrode as cathode, the cogeneration of ozone and hydrogen peroxide in the same electrochemical cell was studied. Water was 20 oxidized to ozone on anode while oxygen was reduced to hydrogen peroxide on cathode. The cell configurations,voltages, cathode substrate and electrolysis time effect on the current efficiency for ozone and hydrogen peroxide was discussed. The highest current efficiency for ozone and hydrogen peroxide reached upto 6.5% and 12.3%, respectively. Key words: Environmental engineering; ozone; hydrogen peroxide; electrochemistry; 25 cogeneration 0 引言 臭氧(O )和过氧化氢(H O )都是较强的氧化剂，在环境工程、化学化工、农业等领域有 3 2 2 着广泛的用途[1-3] 。臭氧的产生往往采用对氧气或者空气高压放电法，产生的臭氧在用于水 30 处理时仍旧需要通过布气装置将臭氧溶解于水中[4,