铁氰化钴铜复合膜修饰电极制备及对肼的电催化毕业论文.docVIP

本科毕业论文（设计） 题 目: 铁氰化钴/铜复合膜修饰电极的制备 及对肼的电催化专 业： 化 学 姓 名： 指导教师： 职 称： 副教授 答辩日期： 二O一一年六月四日 在络合剂EDTA的存在下，采用循环伏安法从含有Cu2+、Co2+、K3Fe(CN)6的酸性溶液中制备了铁氰化钴/铜修饰复合陶瓷碳电极(Co/CuHCF/CCE)，研究了该修饰电极的电化学性质以及对N2H4的电催化氧化行为。结果表明，溶液中同时存在Cu2+ 和Co2+ 离子时，沉积物不是铁氰化钴和铁氰化铜的简单混合物，可能是Cu2+ 进入了铁氰化钴的晶格结构中从而生成了钴/铜混合金属铁氰化物。且该修饰电极对N2H4具有显著的电催化作用。在优化条件下，安培法检测N2H4的线性范围为4.61 × 10-6 ～ 4.38 × 10-2mol·L-1，检出限为2.0 × 10-7 mol·L-1，灵敏度为143.1 μA·mM-1。 铁氰化钴–铜；化学修饰电极；电催化；N2H4 Electrochemical characterization and electrocatalytic activity of a mixed cobalt/copper hexacyanoferrate film modified electrode Abstract: In the presence of EDTA, a Co/CuHCF/CCE modified composite ceramic carbon electrode(Co/CuHCF/CCE) was fabricated using cyclic voltammetry (CV). The resulting electrodes exhibited a high electrocatalytic activity towards the reduction of hydrazine (N2H4). The electrochemical behavior of N2H4 at this modified electrode was also investigated by cyclic voltammetric and amperometric techniques. The results showed that when a deposited solution contained Co2+ and Cu2+ ion, the modified film was not a simple mixtures of CoHCF and CuHCF, Maybe Cu2+ came into crystal lattice structure of Co2+ and builded a mixed Co-Cu hexacyanoferrate film. The modified electrode exhibited high electrocatalytic activity for the deoxidize of N2H4. under the optimal conditions, a linear dependence of the catalytic current versus N2H4 concentration was obtained in the range of 4.61 × 10-6 ~ 4.38 × 10-2 mol?L?1 with a detection limit of 2.0 × 10-7 mol?L?1, and a sensitivity of 144.2 μA·mM-1. Key words: cobalt–copper hexacyanoferrate; chemically modified electrode; electrocatalysis; hydrazine 引言 肼, 又称联氨为无色油状液体, 有刺激性氨味，易溶于水及醇，不溶于氯仿和醚类，毒性强，对健康和环境均有显著的危害。在健康方面，吸入肼的蒸气激鼻和上呼吸道。可出现头晕、恶心和中枢神经系统兴奋；对眼有刺激作用，可致眼的永久性损害；对皮肤和粘膜有强烈的腐蚀性 能引起肝脏和血液的损伤。在环境危害方面，是一种重要的有机化工中间体[1]，广泛用于医药、农药、染料、塑料助剂、显像剂、抗氧剂的原料及大型锅炉水的去氧剂。其排放的工业废水、废气的排放会对环境造成