铂镍基纳米晶的制备和结构设计概要1.pptVIP

* * * * * Synthesis and nanostructure-designing of PtNi-based nanocrystals Seminar contest of “ Synthetic Chemistry of Materials” Members: Yao Zhenguo，Chen Han，Dai Xueping， Du Yuexiu，Gong Xuewen，Jia Shasha， Li Weiwei，Ren Yuyu，Sun Ce， Zhang Ke， Song Yiling，Wu Qingqing，Ye Jiaming CONTENTS Introduction Introduction 1 Summary Summary 3 Recent Research Recent Research 2 Introduction * Introduction PtNi-based Nanocrystals For Oxygen Reduction Reaction (ORR) Influence of the surface morphology on specific activity of PtNi-based nanocrystals V.R. Stamenkovic et al , Science, 2007, 315(5811):493-7. ORR * Introduction The desirable morphology of PtNi-based Nanocrystals Sphere ? NO ! Octahedron Dodecahedra Tetrahexahedron ● ● ● ● Recent Research * Octahedron Synthetic Methods: Solvothermal Pt(acac)2 Ni(acac)2 Dimethylformamide(DFM) PtNi nanoparticles 120 ℃ 42 h Precursors Reducing agent and Solvent Gan L et al, Science, 2014, 346(6216):1502-6. Octahedron Mechanism: Element-specific anisotropic growth Gan L et al, Science, 2014, 346(6216):1502-6. Growing along100 directions Ni-richer phase deposition * Green Yellow Brown Black-RD3 Black-RD10 Black-RD30 * Dodecahedra Synthetic Methods: Hot injection Peidong Yang et al, Nature Materials, 2016. Precursor: H2PtCl6, Ni(NO3)2 Oleylamine * Dodecahedra Mechanism Growing along 111and 200directions Ni-richer phase deposition Pt migration and enrichment Peidong Yang et al, Nature Materials, 2016. * Tetrahexahedron Synthetic Methods Pt(acac)2 Ni(acac)2 Oleylamine (OM)/Oleic acid (OA) DTAC PtNi nanoparticles 180 ℃ 3 h Precursors Surfactant and Solvent OM/OA =1:1 OM/OA =4:1 Ding J et al. Nano Letters, 2016, 16. * Rhombicuboctahedron Synthetic Methods: Solid-state dewetting of bilayer films Seo O et al. Journal of Alloys Compounds, 2016. Driving force: Surface tension and reduction of interfacial energy Substrate Ni Ni Pt Pt 800 ℃ * Rhombicuboctahedron Seo O et al. Journ