疏水型白炭黑的制备及表征论文.docVIP

疏水型白炭黑的制备及表征论文 安徽工程大学毕业设计（论文） 疏水型白炭黑的制备及表征 刘峰 （安徽工程大学生物与化学工程学院 芜湖 241000 ） 摘 要 本文主要是对沉淀法制备的白炭黑以PEG6000为改性剂，进行表面改性，以期增大产品的DBP吸油值，提高产品的分散性。重点考察了改性剂用量、反应温度、反应时间、分散液用量对白炭黑表面改性效果的影响。通过测定白炭黑DBP吸油值作为主要的性能指标用于确定白炭黑的改性效果。研究结果表明，当改性剂用量15 %、反应温度80 ℃、反应时间2.5 h、分散液用量为80 mL，白炭黑的DBP吸油值达到3.00 mL/g。最后对样品的性质特征进行了表征，XRD表征为高度无定形结构。FT-IR谱图表明，采用PEG6000改性后的二氧化硅表面得到明显改善。 关键词：稻壳灰；白炭黑；PEG6000；表面改性 I 刘峰：疏水型白炭黑的制备及表征 Preparation and characterization of hydrophobic silica Liufeng (College of Biology and Chemical Engineering, Anhui Polytechnic University,Wuhu,Anhui,241000) Abstract In this paper, in order to increase the DBP value and improve the dispersibility of the product, the deposition of silica was modified with PEG6000. The modifier dosage, reaction temperature, reaction time and dispersion liquid dosage were used to analysis the effect of silica surface modification. The DBP value was as the main index to determine the effect of modification of silica. The result showed that when the dosage of modifier 15 %, reaction temperature 80℃, reaction time 2.5h and the dispersion amount was 80mL, the silica DBP value is 3.00mL/g. And the X-ray diffraction pattern of silica powders was shown a typical amorphous structure. The structure and properties of silica were characterized by FT-IR showed that the prepared silica via PEG6000 modified was improved obviously. Keyword: Rice husk ash；Silica；PEG6000；Surface modification II 安徽工程大学毕业设计（论文） 目 录 引 言 ........................................................................................................................................................ - 1 - 第1章 绪论 .............................................................................................................................................. - 2 - 1.1 稻壳灰概述 ................................................................................................................................. - 2