标准电极电势可以用来计算化学电池或原电池电化学势或电极电势.docVIP

标准电极电势可以用来计算化学电池或原电池的电化学势或电极电势。 本表中所给出的电极电势以标准氢电极为参比电极，溶液中离子浓度为1mol/L，气体分压为100kPa，温度为298K。[1][2][3][4] 半反应 Eo (V) Li+ + e? → Li(s) ?3.05 Rb+ + e? → Rb(s) ?2.98 K+ + e? → K(s) ?2.93 Cs+ + e? → Cs(s) ?2.92 Ba2+ + 2e? → Ba(s) ?2.91 Sr2+ + 2e? → Sr(s) ?2.89 Ra2+ + 2e? → Ra(s) ?2.80 Ca2+ + 2e? → Ca(s) ?2.76 Na+ + e? → Na(s) ?2.71 Mg2+ + 2e? → Mg(s) ?2.38 Al(OH)4- + 3e? → Al(s) + 4OH? ?2.33 Al(OH)3 + 3e? → Al(s) + 3OH? ?2.31 H2 + 2e? → 2H? ?2.25 Ac3+ + 3e? → Ac(s) ?2.20 Be2+ + 2e? → Be(s) ?1.85 Al3+ + 3e? → Al(s) ?1.66 Ti2+ + 2e? → Ti(s) ?1.63 TiO(s) + 2H+ + 2e? → Ti(s) + H2O ?1.31 Ti2O3(s) + 2H+ + 2e? → 2TiO(s) + H2O ?1.23 Ti3+ + 3e? → Ti(s) ?1.21 Mn2+ + 2e? → Mn(s) ?1.18 V2+ + 2e? → V(s) ?1.13 Nb3+ + 3e? → Nb(s) ?1.099 Sn(s) + 4H+ + 4e? → SnH4(g) ?1.07 SiO2(s) + 4H+ + 4e? → Si(s) + 2H2O ?0.91 B(OH)3(aq) + 3H+ + 3e? → B(s) + 3H2O ?0.89 TiO2+ + 2H+ + 4e? → Ti(s) + H2O ?0.86 2 H2O + 2e– → H2(g) + 2 OH– ?0.83 Zn2+ + 2e? → Zn(s) ?0.76 Cr3+ + 3e? → Cr(s) ?0.74 [Au(CN)2]– + e– → Au(s) + 2 CN– ?0.60 PbO(s) + H2O + 2e? → Pb(s) + 2OH? ?0.58 2TiO2(s) + 2H+ + 2e? → Ti2O3(s) + H2O ?0.56 Ga3+ + 3e? → Ga(s) ?0.53 H3PO2(aq) + H+ + e? → P(s) + 2H2O ?0.51 H3PO3(aq) + 3H+ + 3e? → P(s) + 3H2O ?0.50 H3PO3(aq) + 2H+ + 2e? → H3PO2(aq) + H2O ?0.50 Fe2+ + 2e? → Fe(s) ?0.44 2CO2(g) + 2H+ + 2e– → HOOCCOOH(aq) ?0.43 Cr3+ + e? → Cr2+ ?0.42 Cd2+ + 2e? → Cd(s) ?0.40 PbSO4(s) + 2e– → Pb(s) +SO42? ?0.36 GeO2(s) + 2H+ + 2e? → GeO(s) + H2O ?0.37 In3+ + 3e? → In(s) ?0.34 Tl+ + e? → Tl(s) ?0.34 Ge(s) + 4H+ + 4e? → GeH4(g) ?0.29 Co2+ + 2e → Co(s) ?0.28 H3PO4(aq) + 2H+ + 2e? → H3PO3(aq) + H2O ?0.28 V3+ + e? → V2+ ?0.26 Ni2+ + 2e? → Ni(s) ?0.25 As(s) + 3H+ + 3e? → AsH3(g) ?0.23 MoO2(s) + 4H+ + 4e? → Mo(s) + 2H2O ?0.15 Si(s) + 4H+ + 4e? → SiH4(g) ?0.14 Sn2+ + 2e? → Sn(s) ?0.13 O2(g) + H+ + e? → HO2?(aq) ?0.13 Pb2+ + 2e? → Pb(s) ?0.13 WO2(s) + 4H+ + 4e? → W(s) + 2H2O ?0.12 CO2(g) + 2H+ + 2e? → HCOOH(aq) ?0.11 Se(s) + 2H+ + 2e? → H2Se(g) ?0.11 CO2(g) +