锂离子电池硅碳负极的制备工艺及的研究.docVIP

本科毕业设计(论文) 学 院 专 业 年级班别 200（） 学 号 学生姓名 指导教师 2013 年 月Abstract Li-ion battery has been frequently used in people’s daily life, work and military activities. Obviously, its performance and preparation technology have been studied. This paper aims to illustrate the structural characteristics, working principle and performance advantages of the lithium-ion battery by focusing on the research study, the working principle and the performance advantages of the silicon - graphite composite cathode materials. In addition, the thesis introduces the preparation of the graphite composite cathode materials by using the high energy mechanical ball-milling method, exploring the different ball milling time, the calcination temperature and other conditions that will affect the negative electrode materials. Moreover, the means of the constant current charge-discharge, cyclic voltammograms and other electrochemical testing methods are applied to test the battery, and the tests of the physical and chemical properties, such as XRD, SEM are applied to characterize the grain size, the crystallization conditions, the microstructure, the phase composition and combination of the compound powder. The experimental result show that the process parameters of the ball-milling time of 12 h and the calcination temperature of 650 ℃, the preparation of silicon - graphite composite can get the satisfying electrochemical properties under the condition of less energy consumption. Keyword：Li-ion battery, negative electrode materials, ilicon - graphite composite materials, preparation technology 目录 1 前言 1 1.1 锂离子电池概述 1 1.1.1 锂离子电池发展历程与现状 1 1.1.2 锂离子电池的特点 2 1.1.3 锂离子电池的结构和工作原理 3 1.2 锂离子电池的正极材料 5 1.2.1 钴酸锂（LiCoO2） 5 1.2.2 镍酸锂（LiNiO2） 6 1.2.3 锰酸锂（LiMn2O4和LiMnO2） 6 1.2.4 磷酸铁锂（LiFePO4） 7 1.2.5 钒的氧化物 7 1.3 锂离子电池负极材料 7 1.3.1 碳类负极材料 8 1.3.2单质硅负极材料 9 1.3.3其它负极材料 10 1.4 硅碳复合负极材料 11 1.4.1 硅-石墨复合材料 11 1.4.2 硅-热解无定形碳复合材料 12 1.4.3 硅―碳纳米管 12 1.4.4 硅-石墨烯 13