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THEORIES OF REATION RATES Peel District School Board反应速率理论皮尔区教育局
THEORIES OF REACTION RATES Section 6.3 COLLISION THEORY Reaction occurs when two reactant particles collide with each other Theory explains reactivity at a molecular level FACTORS THAT AFFECT RATE OF REACTION Concentration Surface Area Temperature Catalysts CONCENTRATION Rate of reaction will increase if there are more collisions per unit of time More particles in a given volume (concentration = mass/volume) will increase rate Therefore, higher concentration = faster reaction rate CONCENTRATION Increasing the # of reactant particles in a given volume will increase the # of collisions! versus SURFACE AREA Recall flour burning fire ball demo! Greater surface area means more collisions can occur Explains why campfires are lit with paper and twigs not logs SURFACE AREA versus As S.A increases, there is more exposure of reactant particles, which increases number of collisions! TEMPERATURE Higher temperature means more kinetic energy which speeds up the rate of the reaction TEMPERATURE Higher temperature means reactant particles have higher K.E., So there are more collisions with sufficient energy! versus Slower particles Faster particles We’ll come back to CATALYSTS later! BEYOND COLLISION THEORY Not every collision will result in a reaction In order for collisions to result in a reaction, the collision must be effective Two criteria must be met: 1) Proper orientation of reactants is required 2) Sufficient collision energy is needed CONDITIONS TO BE MET… 1) PROPER ORIENTATION Particles must collide with proper orientation relative to one another Known as collision geometry See Figure 6.9, page 290 Only 1 of the 5 situations actually leads to a reaction 1) Correct Orientation Also called having the correct “collision geometry” Animation Collision Geometry /physsci/chemistry/essentialchemistry/flash/collis11.swf CONDITIONS TO BE MET… 2) SUFFICIENT ENERGY There must be enough energy to break the bonds in the reactants and begin to reform bonds in the produc
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