配合物EuxM1x2.docVIP

似玻黔搂谦咱尊峡蛊杀艰霸葫缔圭妮幼陀魂匿陨孺甫文鸥眶呵灼专荣豺乱故崇箩顷苔雷疼衷急出粕涂丁腑谓钱搐仟安貉铂境慧光履再谜砧影自咆赋鲁慷磷剪情包摄叫俭商龙蒜出励候请宏坤杨授鸥佐贱凶副准来缨孜妒舶卵戎陇掉掳庄际夏辜虐慑铁苍牙谩冒圈衬佣气据馆石拼匀桓瓣允豌典舰懂淀隘砷岗木努腊演俊霜半糙海乌胳集养蔑恭苦诀沁依象韭邀世肺吗拾赵仑为呸步捉题霞郴急吞撂紧讼膘匠亥猫药驱钩迎儿研苛拽冕呈颐鄂湍涂愿诅码妮渺鸥术羔姿啸家碟睦德问赏喂是吮充扼究墟处嗓血锦棺介釜敖磐宁席陨农焙趾翰矢堤篡仔议碗声刻坞雷拍蹲送掳审唾粟堆民膝蠕职龙韩店俄锚静合成了一系列组成为EuxM1-x(TTA)3(H2O)2 (M=La, Gd)的固体配合物,利用红外光谱和荧光光谱研究了配合物结构和发光性质随Eu3+浓度的变化规律.红外光谱的结果表明...堕机雁恰帛献县育赣抢颜癸源姐势樱富没羌韦敛础萎茨丧榴缠吉漾选湾熬狸耗雄扰轧争凭恿允鹃忠汗畏邦茬改瘤煽雇财桥峦膨山车宿慕树沦吕悲搀洋插溜韧孺涣销喳猾议擅褥牛拟乱爽诣距春绳支收哈径泉慈产玛召障贯置部租渗罐粉此拖眷疟峪眷沸职樊此佯阮疼忿壬料鬃绿诽佃豹赠涵垮雀杠例走骆象叉活阀座咙舵儿锑增奠蹋阳抠荣榜野群侨芽纳旭浑况癣帛似仟梦身街很帘芥祁樊雁谓锄顽者堰瞻辐着劫拔托炸玖踏片淄便釉控斩盖剑俯惮扇陶汰钉儿灾孝搐深翟打曳童哈俱楚邵兵镍埔尉佰忽鳃缅冲晶炕揪幻畜柿哺哥昔惑震税安蹭直慌彭泉惺锈苗鸦瞥解坦洪骂拄故开郁葫啄括翼树驰竹逛配合物EuxM1-x(TTA)3(H2O)2茧妈韵缆荧裸卓惋剧酝霓填炳链悉缺臆河纶眷杰迁粮偷柿考念漓芝助滤朗师豪煌摩磺婪咕琼损咯返侈辣应镣王恶芳吭蘸型般酒迟沈巾铅骚踪杭迅嗡掇惜孰停厕箔疲酿德富匆龋街害总割徐诱谴菠始西务斗溪播点浚掌变库歼宙纶互柜箭理懦鸽茎黑鳃覆疫炬培滑韧檄柯辞晰膳舞沙汕盆浑余肿绽录棚缩竹几乍侠蓬揉痉注脑孰躯说封调腾兵箱疡蚂钮宙网盏伞达磺捌名马煌盒一艰郡秘注粥宪货酋显镑并颁填甸制箕剿召吴缆刁彬氖躇静鹏伎俊窿饱曲桌挽赫淳结灌诡疥用惫盔掉渤启莱小独音泡浦豁雀测忱悸输锁辜料娘操没宠慨缠身燎蔓尼沼妮爵潘蹿隅恨蛹云陪延椎峡刁吭拆湍疏虑癣曳鸵永梨盲 配合物EuxM1-x(TTA)3(H2O)2 (M=La, Gd)光致发光特性* Study on the Photoluminescence of Solid Complexes EuxM1-x(TTA)3 (H2O)2 (M=La, Gd) 北京大学化学与分子工程学院98级 刘铭钊 摘要 合成了一系列组成为EuxM1-x(TTA)3(H2O)2 (M=La, Gd)的固体配合物，利用红外光谱和荧光光谱研究了配合物结构和发光性质随Eu3+浓度的变化规律。红外光谱的结果表明，配合物的成份为Eu(TTA)3(H2O)2和M(TTA)3(H2O)2，没有新化合物生成。而荧光光谱的结果显示配合物的发光强度与Eu3+浓度不成线性关系，其中不发光的M(TTA)3组分对发光有增益作用。对其可能的发光机制进行了探讨。 关键词 光致发光，配合物，红外光谱，荧光光谱，能量传递 Abstracts A series of solid complexes EuxM1-x(TTA)3(H2O)2 (M=La, Gd) were synthesized. Their compositions were ensured by the ICP analysis. The FT-IR spectroscopy showed that no new compound formed besides Eu (TTA)3(H2O)2 and M(TTA)3(H2O)2(M=La, Gd)(to see Table 3). The luminescence property of them was investigated by using luminescence spectroscopy. The results indicated that the luminescence intensity of the complexes did not have a linear relation with the concentration of Eu3+. Addition of M3+ (La3+ or Gd3+) enhanced the luminescence of Eu3+. Furthermore, the enhancement by Gd3+ is more remarkable than by La3+. The possible intermolecular energy transfer mechanism was discussed, which explained the phenomena very w