电刷镀NiZrO2纳米复合镀层及其磨损腐性能研究.doc

电刷镀Ni-ZrO2纳米复合镀层及其磨损腐蚀性能研究 摘 要 纳米复合镀是20世纪90年代兴起的一种新型材料表面改性技术，它用纳米颗粒代替了普通复合镀中所使用的微米颗粒，是复合镀的发展趋势。本文采用纳米电刷镀技术在Q235基体表面镀覆Ni-ZrO2纳米复合镀层，重点对添加不同浓度的ZrO2纳米颗粒镀层性能进行分析。 纳米电刷镀制备过程包括试验前预处理（打磨、电净、活化）、镀打底层、镀复合镀层三步。在镀复合镀层阶段，控制反应温度50℃，pH值6，通过控制电量来控制镀层厚度。制备成功的镀层经洗净、烘干后进行检测。 从镀层表面形貌、摩擦摩损性能和耐腐蚀性能三个方面重点研究在镀液中添加不同浓度ZrO2纳米颗粒对镀层性能的影响。试验表明，当添加的ZrO2纳米颗粒浓度较低时（0.5 g/L-1.5 g/L），试件的摩擦系数、磨损量和划痕宽度均保持在一个较小的范围内；当ZrO2纳米颗粒浓度较高（2.0 g/L）时，试件的摩擦系数、磨损量和划痕宽度明显增大。在耐腐蚀性能方面，采用静态浸泡失重法测腐蚀量。试验表明随着ZrO2纳米颗粒浓度的增加，其耐腐蚀性也随之提高。 关键词：镍基复合镀层；纳米电刷镀；二氧化锆；耐磨损性能；耐腐蚀性能 Research for Wearing Resistance and Corrosion Resistance of Ni-ZrO2 Nano-composite Coatings Prepared by Brush Electroplating Abstract Nano-composite plating,which occurred in the 90s of 20 century,is a novel surface-finishing method of materials,wherein microparticles used in composite plating were substituted by nano-particles.It is the trend of composite plating.We use the method of nano-composite brush plating coated with Ni-ZrO2 nano-composite coatings on Q235 substrate in this paper,and mainly analyzed Ni-ZrO2 nano-composite coatings’ performance with different ZrO2 content. The preparation for nano-composite coatings include three steps,such as pretreatment(polishing,electro-clean and activate),nickel pre-plate and preparation of Ni-ZrO2 nano-composite coatings.We should keep 50℃,pH = 6 and electric quantity to control thickness.After we prepared Ni-ZrO2 nano-composite coatings successfully,we need wash and dry it,then detect it. We studied major in Ni-ZrO2 nano-composite coatings which from three aspects include surface performance,wearing resistance and corrosion resistance from different ZrO2 content.And that ,we studied wearing resistance also from three aspects ,such as friction factor,wearing value and scratch width.We found it’s good for coatings’ wearing resistance when density of ZrO2 between 0.5g/L and 1.5g/L;it’s bad for coatings’ wearing resistance obviously when density of ZrO2 exceed 2g/L.And we research corrosion resistance by the met