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Reactions of Alkenes and Alkynes. Well see that the most important reaction of these two functional groups is the addition to the C=C and C≡C multiple bonds of various reagents X-Y to yield saturated products: The addition of halogen acids, HX, to alkenes is a general reaction that allows chemists to prepare a variety of halo-substituted alkane products. Thus, HCl, HBr, and HI all add to alkenes: 4.2 Orientation of Alkene Addition Reactions: Markovnikovs Rule After looking at many such reactions, the Russian chemist Vladimir Markovnikov proposed in 1869 what has become known as Mark