外文翻译煤低温氧化模型.docVIP

英文原文： Coal oxidation at low temperatures: oxygen consumption, oxidation products, reaction mechanism and kinetic modelling The conservation of mas and energy will be applied to the regions depicted in Figures 2a-2c. These consist of the (a) the char, @) the vaporization interface, and (c) the virgin solid. For mass conservation with respect to a control volume, the rate of change of mass within the control volume plus the net rate of mass flow out of the contol volume is equal to zero. The conservation of energy for a control volume states that the rate of change of internal energy within the contol volume plus the net rate of enthalpy out is equal to the net rate of heat addition. Work is neglected, except for flow work, and combustion energy can be treated as an effective heat addition. Constant properties will be assumed for each distinct media, i.e. char and virgin material; and the internal energy is referenced at the initial temperature. The conservation of mas for the solid in Figure 1 is given by (1) where is the mass of change of the solid, A is the surface area, And is the mas flow rate of the gasified products per unit area. Hence, is the mas loss rate per unit surface area, or which is more commomly referred to as the burning rate (per unit area). Eq.(1)is not essential to the governing equations which follow, but is only presented to show the relationship between the rate of fuel gasses which flow out of the system and the rate of maw loss of the solid. Conservation of mass for the char By considering the conservation of mass for the char layer in Figure 2a, and assuming that the vaporized fuel instantaneously leaves the solid, it follows that (2) where pc is the char density, and xh, is the char mass flow rate per unit area from the vaporizationplane. The accumulation of the fuel gases in the char matrix is taken to be negligible, so that the rate of gaseous fuel entering from the vapori