第四章-1--铁电存储.ppt

Ferroelectric Memory Reliability and Qualification Gary F. Derbenwick and Stephen C. Philpy Celis Semiconductor Corporation Colorado Springs, Colorado 80918 (719) 262-5144 gary@ Ferroelectric Memory Storage Dielectric and Ferroelectric Materials and Application Louisiana Tech University Outline I. Introduction II. Theory for dielectric materials III. Theory for ferroelectric materials IV. Application V. Recently development VI. Summary I. Introduction Ferroelectricity is a phenomena which was discovered in 1921. Ferroelectricity has also been called Seignette electricity, as Seignette or Rochelle Salt (RS) was the first material found to show ferroelectric properties. A huge leap in the research on ferroelectric materials came in the 1950s, leading to the widespread use of barium titanate (BaTiO3) based ceramics in capacitor applications and piezoelectric transducer devices . Ferroelectricity Ferroelectricity derives its name from ferromagnetic. A magnetization can be observed that is reversible by applying a certain magnetic field. Ferroelectrics show a reversibility, but dealing with applied electric fields to reverse a material’s polarization. III.Theory for Ferroelectric Ferroelectric material Crystal Symmetry Spontaneous Polarization and Pyroelectric Effect Ferroelectric Domains and Hysteresis Loop Curie Point and Phase Transitions Perovskite Structures Dielectric Hysteresis Theory for Ferroelectric(cont.) Magnitude of Spontaneous Polarization Atomic Arrangement and Ferroelectricity Absolute Sense of Spontaneous Polarization Dimensionality of Ferroelectric Crystals Changes in Properties Near the Curie Temperature Antiferroelectric Materials Representative Ferroelectric Materials Material Preparation and Poling Ferroelectric material A ferroelectric material falls into a group of dielectrics that exhibit spontaneous polarization. Ferroelectrics have extremely high dielectric constants at low applied field frequencies. For example, the dielectric consta