高度对不支持的硫化Co-Mo汽油选择性加氢脱硫催化剂二硫化钼形态学的影响：（Highly selective hydrodesulfurization of gasoline on unsupported Co-Mo sulfide catalysts Effect of MoS2 morphology）.pdfVIP

Applied Catalysis A: General 533 (2017) 99–108 Contents lists available at ScienceDirect Applied Catalysis A: General j o u r n a l h o m e p a g e: w w w. elsev /locate/apc ata Highly selective hydrodesulfurization of gasoline on unsupported Co-Mo sulfide catalysts: Effect of MoS2 morphology Ping Li a,b , Yandie Chen a , Cen Zhang a , Baokun Huang a , Xinyi Liu a , Tiefeng Liu a , Zongxuan Jiang a,∗ , Can Li a,∗,1 a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,457 Zhongshan Road, Dalian 116023, China b University of Chinese Academy of Sciences, Beijing 100049, China a r t i c l e i n f o a b s t r a c t Article history: To remove sulfur-containing molecules from gasoline via hydrodesulfurization (HDS) while minimizing Received 27 November 2016 olefin hydrogenation is quite difficult. In this work, we report that an unsupported Co-Mo catalyst can Received in revised form 3 January 2017 achieve high HDS activity with low activity in olefin hydrogenation. The HDS selectivity of the Co-Mo Accepted 10 January 2017 catalyst is fourfold that of CoMo/-Al O for both model gasoline and full-range FCC gasoline. For Co-Mo 2 3 Available online 16 January 2017 sulfide catalysts, we found that the MoS2 slab morphologies such as curvature, stacking number and slab length were important fa