二氧化碳加氢低烯烃高表面积K-promoted批量Fe-catalyst：（CO2 hydrogenation to lower olefins on a high surface area K-promoted bulk Fe-catalyst）.pdfVIP

Applied Catalysis B: Environmental 200 (2017) 530–542 Contents lists available at ScienceDirect Applied Catalysis B: Environmental j o u r na l h o m e pa g e : w w w. elsev /locate/apc atb CO2 hydrogenation to lower olefins on a high surface area K-promoted bulk Fe-catalyst Carlo Giorgio Visconti a,∗ , Michela Martinelli a , Leonardo Falbo a , Antonia Infantes-Molina a,b , Luca Lietti a,∗ , Pio Forzatti a , Gaetano Iaquaniello c , Emma Palo c , Barbara Picutti d , Fabio Brignoli d a Politecnico di Milano, Dipartimento di Energia, Via la Masa, 34, 20156 Milan Italy b Universidad de Málaga, Departamento de Química Inorgánica, Cristalografía y Mineralogía, Facultad de Ciencias, Campus de Teatinos, 29071 Málaga Spain c KT- Kinetics Technologies SpA, Maire Tecnimont Group, Viale Castello della Magliana, 75, 00148 Rome Italy d Tecnimont SpA, Maire Tecnimont Group, Via Gaetano de Castillia, 6/A, 20124 Milan Italy a r t i c l e i n f o a b s t r a c t Article history: A high surface area K-promoted iron-based catalyst is prepared by thermal decomposition of ammonium Received 19 April 2016 glycolate complexes, followed by impregnation with an aqueous solution of potassium carbonate, drying Received in revised form 4 July 2016 and calcination. It is found that the duration of the calcination has a dramatic effect on the textural and Accepted 25 July 2016 structural properties of the obtained material, as well as on the iron oxidation state. Fast calcinations Available online 26 July 2016 allow to synthetize