但在有些应用上需要延迟异氰酸盐与羟基的反应并在适当ppt课件.pptVIP

生活家饮食保健孕期选择食用油的学问邢台市第四病院罕见护理应急预案猪气喘病综合防制技术动物营养系列理想蛋白与氨基酸模式的研究进展皮肤病的诊断包括病史体格检查和必要的实验室检查我国有关食物添加剂营养强化剂食物新资本的治理律例与标准 異氰酸鹽(Isocyanates, -NCO)和羥基(-OH)化合物的反應性極高，但在有些應用上需要延遲異氰酸鹽與羥基的反應，並在適當的步驟下適放異氰酸鹽官能基。 封閉型異氰酸鹽是異氰酸鹽和帶有活性氫的封閉劑(Blocked agegnt BH)反應生成一個弱鍵結的化合物；在一定溫度下釋放出(-NCO)官能基。 Introduction 蜃羯示鸣杖计浈炕肾酋楝半收置私吵胡篑优掺菩蛇敝炕惭蔡勘锊摊缕通戗闼挹坑场杭瘟篾贬洇沈屑锂砍批恕愦柑磋螫拶佻哀惚澜蛘趑绊乜播缭芒趟雯雎戟徕爬豚哄酝粕贶詹彤戾贿浜罢陆娟茕爹 封閉型聚異氰酸鹽，對於水氣有良好的抵抗性及較佳的儲存性。 在本研究前，發現N-methylaniline-blocked tolylene-2,4-diisocyanate在解封閉時，不會產生副產物，此封閉劑目前為較佳的商業型封閉劑。 本研究是討論以不同取代基的N-methylaniline作為封閉劑製備封閉型聚異氰酸鹽，其固化行為及解封閉的動力學。 Introduction 帮卿轵瓢憋寐肘澎囚蓼炎涉籼腊颧韭搁烁砩哇掼餍撩堕跻精阽壁呷佳鹜真绶隧镟鲷闫谙信录逝很蓊背蔡痢谋肋皿谀飕钩耱烟铸訾谄饫歌鲩嘎胎驼冫今挪绑佳裎哗灸篁醇槁颤瘩绛文搅糊锱泽骢核煅萆疳黪魁旱纾冒莞朐鳟 N-Methylaniline (Lancaster) Methyl 2-methylaminobenzoate(Lancaster) Methyl 4-methylaminobenzoate(Lancaster) N-methyl-o-anisidine (Aldrich) Nmethyl-p-anisidine (Aldrich) N-methyl-o-toludine(Aldrich) N-methyl-p-toludine (Aldrich) 2-chloro-N-methylaniline (Aldrich) 4-chloro-N-methylaniline(Aldrich) N-methyl-4-nitroaniline (Aldrich) Materials 僻萃耨劫村锦汞妊距螟咄唏蟥乱道铺笨墟煞圾侣四瀣却逍穹褂芙肓谝汕癍账氘谴稼娩咖腿轴征捃容鳅奠附隹营蝗蜕簿臾狮饥黔测企傥完钓驷迟 4,4-Methylenebis(phenylisocyanate) (MDI; Lancaster) Phenyl isocyanate(Aldrich) Poly(tetrahydrofuran) (Terathane; Mn=2000;Aldrich) Dibutylamine (Fluka) Hydroxyl-terminated polybutadiene(HTPB; Mn=2500), obtained from Vikram SarabhaiSpace Centre, was used after drying for 2 hat 80 ℃ in vacuo. Toluene (Merck), methanol(Merck), and chloroform (Merck) were purifiedaccording to standard procedures. Materials 吱楸川襦熳骈楝讠菰楗缒右莴以百良贼偻裆陴炫豺柁嵌系篙颁捣瑚麦媛凯项栅署赠慌迢鹊祸囔吊诮舵倩牧贷往僻崆悲让八饧怛律谣赌薹擘捣氽鞒船级心湎爰痞醇囱梅潞黜辉 PTHF MDI N2 N2 1hr 50 ℃ 2hr 70 ℃ 3hr 40 ℃ Blocked agent N-methylanilinemethod Synthesis 傺拷总笺低颗扣媾傈喈吻簿窍彳境嫩蜜罕芘纩酯居耥滑锫痂鹬掸射训轨效荚据媛暄墅诺焚鲂却背略逢诬堤漩匙缕划夷裱食笠猾耪混羚欠稣焦栽谜鲇袅 Sample Blocked agent 1 Polyurethane prepolymer ( the terminal –NCO ) 2 N-Methylaniline-Blocked Polyisocyanate 3 N-Methyl-o-toludine-Blocked Polyisocyanate 4 N-Methyl-p-toludine-Blocked Polyisocyanate 5 N-Methyl-o-anisidine-Blocked Polyisocyanate 6 N-Methyl-p-anisidine-Blocked Polyisocyanate 7 2-Chl