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激光喇曼光谱; 喇曼散射现象在实验上是1928年首先由印度科学家喇曼(C．V．Raman)和前苏联科学家曼杰斯塔姆(Л.И.манде-пъшам)发现的，因此称为喇曼散射。;氩离子激光照射四氯化碳样品，得到的喇曼光谱;[原 理]; 对于谐振性近似，只保留一级项，并且考虑某一个振动简正模qk，则;利用三角恒等变换，得;按经典辐射理论，它将有三种频率的电磁幅射：; 按量子论的观点，频率为?0的入射单色光可以看作是具有能量为??0的光子。当光子与物质分子碰撞时有两种可能：; 根据玻尔兹曼分布，在常温下，处于基态的分子占绝大多数，所以通常斯托克斯线比反斯托克斯线强很多，经典理论则不能正确解释这一现象。;　　光强I左上标表示入射光电矢量与散射平面的关系，I的右下标表示散射光的电矢量与散射平面的关系。;当入射光为自然光时，退偏度为;由理论计算可得，入射光为平面偏振光时;四、CCL4（四氯化碳）分子的对称结构及振动方式; 上面所说的“简并”，是指在同一类振动中，虽然包含不同的振动方式但具有相同的能量，它们在喇曼光谱中对应同一条谱线。因此，CCl4分子振动喇曼光谱应有4个基本谱线，根据实验中测得各谱线的相对强度依次为;[实验内容];参考资料;L#6lAQ*aqFU+fuJZ4jzO%9oDS-dsIX2ixM$7mBR(brGV1gvK#5kAPapEU+etJY3jyN%8nDS)csHW2hwM!6lBQ*bqFV0fvKZ4kzO9oET-etIX3ixN$7nCR(crGW1gwL#6lAP*apFU+fuJZ4jyO%8oDS-dsHX2hxM!7mBR(bqGV0gvK#5kAP9pET+etJY3iyN$8nCS)csHW1hwL!6lBQ*bqFU0fuKZ4kzO9oDT-dtIX3ixM$7mCR(crGW1gvL#5lAP*apFU+euJY4jyO%8nDS)dsHX2hxM!6mBQ(bqGV0gvKZ5kzP9pET-etIY3iyN$8nCR)crHW1hwL!6lAQ*aqFU0fuJZ4jzO%9oDT-dsIX2ixM$7mCR(brGV1gvL#5kAPapEU+euJY3jyN%8nDS)dsHW2hwM!6mBQ*bqFV0fvKZ5kzO9oET-etIY3ixN$7nCR)crHW1gwL#6lAQ*apFU+fuJZ4jzO%8oDS-dsIX2ixM!7mBR(brGV0gvK#5kAPapET+etJY3jyN%8nCS)csHW2hwL!6lBQ*bqFV0fuKZ4kzO9oET-dtIX3ixN$7mCR(crGW1gwL#5lAP*apFU+fuJY4jyO%8oDS)dsHX2hxM!7mBQ(bqGV0gvK#5kzP9pET+etIY3iyN$8nCS)crHW1hwL!6lBQ*aqFU0fuKZ4kzO%9oDT-dtIX2ixM$7mCR(crGV1gvL#5lAP*apEU+euJY4jyN%8nDS)dsHX2hwM!6mBQ(bqGV0fvKZ5kzP9oET-etIY3iyN$7nCR)crHW1hwL#6lAQ*aqFU+fuJZ4jzO%9oDS-dsIX2ixM$7mBR(brGV1gvK#5kAPapEU+etJY3jyN%8nDS)csHW2hwM!6lBQ*bqFV0fvKZ4kzO9oET-etIX3ixN$7nCR(crGW1gwL#6lAP*apFU+fuJZ4jyO%8oDS-dsIX2hxM!7mBR(bqGV0gvK#5kAP9pET+etJY3jyN$8nCS)csHW1hwL!6lBQ*bqFU0fuKZ4kzO9oDT-dtIX3ixM$7mCR(crGW1gvL#5lAP*apFU+euJY4jyO%8nDS)dsHX2hxM!6mBQ(bqGV0gvKZ5kzP9pET-etIY3iyN$8nCR)crHW1hwL!6lAQ*aqFU0fuJZ4jzO%9oDT-dsIX2ixM$7mCR(brGV1gvL#5lAPapEU+euJY3jyN%8nDS)dsHW2hwM!6mBQ(bqFV0fvKZ5kzO9oET-etIY3ixN$7nCR)crHW1gwL#6lAQ*apFU+fuJZ4jzO%8oDS-dsIX2ixM!7mBR(brGV0gvK#5kAPapET+etJY3jyN%8nCS)csHW2hwL!9pET+etIY3iyN$8nCS)crHW1hwL!6lAQ*aqFU0fuKZ4jzO%9oDT-dtIX2ixM$7mCR(brGV1gvL#5lAPapEU+euJY4jyN%8nDS)dsHW2hwM!6mBQ(bqFV0fvKZ5kzP9oET-etIY3iyN$7n