NaCl-KCl-MgCl2体系中升华物组分特征和对氯压系统影响.docVIP

NaCl-KCl-MgCl2体系中升华物的组分特征及对氯压系统的影响 朱福兴，马尚润，苗庆东，李开华 （攀钢集团研究院有限公司，钒钛资源综合利用国家重点，四川攀枝花 617000） 摘要：采用Factsage、XRD、SEM等手段对NaCl-KCl-MgCl2体系在电解和未电解两种模式下的升华物组分特性及其对氯压系统的影响进行研究。研究表明，未电解模式下NaCl-KCl-MgCl2熔盐体系的升华物成分与理论计算值吻合，但电解模式下升华物中MgCl2相含量急剧增加，这是镁与氯气的副反应产物MgCl2升华造成的；电解和未电解两种模式获得升华物粒径分布不均匀，且结构不规则，但电解模式获得的升华物粒径明显较未电解模式大，其原因为电解模式下升华物中小液滴作用。升华物对氯压系统的影响主要与硫酸介质反应生成硫酸盐(硫酸氢盐)和HCl气体，缩短氯压机叶轮和氯气管线的使用寿命，生产中需严格把控布袋的孔径和质量，并在袋式过滤器与氯压机中间增加二次过滤装置。关键词：升华物；NaCl-KCl-MgCl2；电解；氯压系统 中图分类号：TF822 文献标志码：A 文章编号：1007-7545（2018）06-0000-00 Component Characteristics of Sublimate and Its s on Chlorine Compressor in NaCl-KCl-MgCl2 Melts ZHU Fu-xing, MA Shang-run, MIAO Qing-dong, LI Kai-hua （State Key Laboratory of Vanadium and Titanium Comprehensive Utilization, Pangang Group Research Institute Co., Ltd., Panzhihua 617000, Sichuan, China） Abstract：Component characteristics of sublimate under different conditions and its effects on chlorine compressor in NaCl-KCl-MgCl2 melts were studied with Factsage, XRD and SEM. The results show that component of sublimate under non-electrolytic condition is consistent with theory vale, but MgCl2 content of sublimate under electrolyte condition rises drastically due to by-product MgCl2 produced via reaction Mg with Cl2 sublimates on electrolyte surface. Particle size and structure of sublimate at different conditions present inhomogeneous and irregularity. However, particle size of sublimate obtained under electrolyte condition is larger than that under non-electrolyte condition because of drop of melts produced under electrolyte condition. Sulfate (disulphate) and HCl obtained through reaction sublimate with sulfuric acid could shorten service life of chlorine compressor impeller and chlorine pipeline. Pore size and quality of cloth bag should be under strict control, and secondary filter added between bag filter and chlorine compressor is feasible. Key words：sublimate; NaCl-KCl-MgCl2; electrolysis; chlorine compressor 氯化镁熔盐电解是制备金属镁的重要方法，尤其在镁热法生产海绵钛企业则是建立全流程镁氯循环和降低海绵钛制造