熔炼工艺及成分对高熔点cu-ni-nb合金组织与导热性能的影响-effect of melting process and composition on microstructure and thermal conductivity of high melting point cu - ni - nb alloy.docx

万方数据 万方数据 （5）时效处理能使合金组织变粗大，析出相增多，合金导热率获得提高。 Cu-30Ni-1Nb-1Fe 合金铸态时二次枝晶间距为 18μm，第二相质量分数为 1.1%， 合 金导 热 率为 20.94W/m·k； Cu-30Ni-1Nb-1Fe 合 金时 效 态时 二 次枝 晶 间距 为 21μm，第二相质量分数为 2.4%，合金导热率为 24.30W/ m·k。 （6）通过正交试验，获得电弧熔炼+水冷铜坩埚冷却制备工艺的最佳成分为 Cu-30Ni-10Nb，其熔点为 1153.30℃，导热率为 36.98W/m·k。 关键字：Cu-Ni-Nb 合金，熔炼工艺，合金组织，合金成分，熔点，导热率 II Abstract Copper cooling jacket is key cooling equipment applied in blast furance and flash smelting furance. The copper cooling jacket can not only achieve strengthening metallurgy, but also protect furance liner and extend the service life of the furance body. The selection of cooling water jacket material is key to determine the effect of furance wall heat transfer in metallurgical furance. It directly affects metallurgical furance life, productive efficiency and energy consumption. The short process flow and the good cooling effect is the advantage of copper cooling jacket with an embedded pure copper tube. It gradually became the best choice of the cooling equipment in the world. However, the pure copper tube of Cu/Cu jacket is melt through easily in casting process. The NiCu alloy tube of Cu/NiCu jacket has low thermal conductivity. The Cu/Steel jacket has some disadvantages. The mutual solubility between Cu and Fe is low. So it is very difficult to make metallurgical bonding between Cu and steel, which cause there is a gap between Cu and steel. The thermal conductivity of steel is low. The embedded pipes of the last two kinds of cast copper water jacket has high melting point. In order to make metallurgical bonding between alloy tube and copper body, the pouring temperature of molten copper must be raised. As a result, molten copper inhales badly and it is difficult to eliminate abscess of casting. Therefor, it is very important to develop the new type alloy with high melting, modrate thermal conductivity, fit the requirement of pouring temperature of pure copper and easy to make metallurgical bonding between the alloy tube and the copper body. Therefor