13a. SSL 应用 Grignard-2014.11.pptVIP

卤化物 化学位移 (ppm) 格氏试剂 化学位移 (ppm) 碘甲烷 -25.09 CH3MgI -13.77 溴乙烷 19.12, 27.01 CH3CH2MgBr -2.12, 12.33 正溴丁烷 12.68, 21.26, 32.23, 34.96 n-BuMgBr 7.59, 13.71, 30.79 , 31.76 溴代环己烷 25.03, 25.72, 37.45, 53.27 C6H11MgBr 24.71, 28.78, 31.11, 34.25 烯丙基溴 31.93, 118.11, 134.67 CH2CHCH2MgBr 57.79, 147.57 溴苯 122.43, 126.72, 129.91, 131.44 PhMgBr 123.00, 124.59, 138.53, 162.98 对甲氧基溴苯 55.33, 112.74, 115.67, 132.16, 158.64 4-MeOC6H4MgBr 55.32, 112.23, 140.72, 153.60, 157.79 对异丙基溴苯 23.47, 33.77, 119.39, 128.06, 131.38, 147.62 4-iso-C3H7C6H4MgBr 23.93, 33.92, 124.02, 139.98, 144.35, 160.10 1-溴代奈 122.65, 125.97, 12