钐掺杂氧化铈-碳酸盐复合电解质的优化和电性能分析-optimization and electrical properties analysis of samarium doped cerium oxide - carbonate composite electrolyte.docx
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钐掺杂氧化铈-碳酸盐复合电解质的优化和电性能分析-optimization and electrical properties analysis of samarium doped cerium oxide - carbonate composite electrolyte
amongSDC,ESBandcarbonate.TheinfluencesoftheamountofESBandcarbonateonH+andO2-conductivitieswererespectivelystudiedbyD.C.fourprobemethod.SEMshowedthatthedistributionofthetwophasesincreasedwiththedecreaseoftheamountofthecarbonate.TheH+andO2-conductionenhancedwiththeincreaseofcarbonateorESB,whichindicatedthatcarbonatefavoredH+andO2-conduction,ESBbenefitedO2-conductivity,andtheinterfaceoftwophasesimprovedH+conduction.KEYWORDS:Dopedceria,Carbonate,Compositeelectrolyte,Protonconduction,Oxygenionconduction,Solidoxidefuelcell目录第一章绪论..................................................................................................................11.1前言.....................................................................................................................11.2燃料电池简介.....................................................................................................11.3固体氧化物燃料电池(SOFCs)概述41.3.1固体氧化物燃料电池的工作原理..............................................................41.3.2固体氧化物燃料电池的特点......................................................................51.4固体氧化物燃料电池的材料.............................................................................51.4.1固体电解质材料..........................................................................................51.4.2阳极材料......................................................................................................91.4.3阴极材料....................................................................................................101.4.4连接体材料................................................................................................111.5固体氧化物燃料电池的发展趋势...................................................................111.6复合电解质在燃料电池中的发展及应用.......................................................122.1前言...................................................................................................................192.2实验部分...........................................................................................................192.
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