稀土掺杂钙钛矿氧化物多晶的结构及电磁特性分析-analysis of the structure and electromagnetic properties of rare earth doped perovskite oxide polycrystals.docxVIP

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稀土掺杂钙钛矿氧化物多晶的结构及电磁特性分析-analysis of the structure and electromagnetic properties of rare earth doped perovskite oxide polycrystals.docx

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稀土掺杂钙钛矿氧化物多晶的结构及电磁特性分析-analysis of the structure and electromagnetic properties of rare earth doped perovskite oxide polycrystals

PAGE PAGE IV 内蒙古科技大学包头师范学院硕士学位论文 Study on the Structure and Electromagnetic Properties of Rare Earth Doping Perovskite Oxide Polycrystallines Abstract Objective To investigate the dependence of the transport properties of manganites on the chemical substitution using rare earth elements of different ionic radius.Method The samples were prepared according to the High temperature solid phase reaction method, its spatial structures was studied by means of XRD diffractometer; and physical properties were measured using SQUID and PPMS instruments. Results （1）The researches of ABO3-type La0.5-xNdxSr0.5CoO3(x = 0,0.05, 0.1,0.15,0.2) polycrystallines show that: doping a small amount ( x ??0.05 ) of Nd3+ ions can improve the Curie temperature of the system; small amount of doped samples exhibit the characteristics of the spin-glass-like state. （2）The researches of A3B2O7-type La1.2-xTbxSr1.8Mn2O7（x=0, 0.05, 0.1, 0.15, 0.2）and La1.3-xGdxSr1.7Mn2O7(x = 0, 0.05, 0.1, 0.15, 0.20) polycrystallines show that : lattice parameters of the samples are decreased due to the incorporation of the Tb and Gd . Both of the low-doped samples in the two series polycrystalline appear the spin-glass behavier，and the ferromagnetic state can be observed in the low temperature region, but, when the doping is larger in samples, the ferromagnetic state will be destroyed. There are a number of extreme points in the thermal magnetic curves. But the ferromagnetic transition will disappear when the doping amount increase further，and become into the insulating state. And the eigen CMR magnetoresistance is observed in the vicinity of the Curie temperature, which is caused by the ferromagnetic - paramagnetic phase transition. The magnetoresistance behavior in low temperature is non-eigen，which is derived from Spin-polarized tunneling and scattering of conduction electron in the boundaries of polycrystalline . Key words: Perovskite oxide；Magnetic transport properties；Doping effects；Lattice d