原子荧光法测定龙山卷丹百合中砷、汞含量.docVIP

原子荧光法测定龙山卷丹百合中砷、汞含量 　　摘要：目的 优化微波消解条件，测定龙山卷丹百合中砷、汞的含量。方法 采用自动微波消解仪，在聚四氟乙烯微波管中用HNO3-H2O2消解龙山卷丹百合样品，并通过原子荧光法分别测定龙山卷丹百合中砷、汞的含量。结果 龙山卷丹百合是砷的含量范围为0.031～0.507 mg/kg，汞的含量最高为0.024 mg/kg，砷、汞的线性方程分别为Y=221.23X+170.72（r=0.995 9）、Y=503.52X-682.43（r=0.999 2）。生产基地的样品中砷、汞元素加样回收率分别为94.32%、92.48%，RSD分别为2.14%、2.70%；育种基地的样品中砷、汞元素加样回收率分别为94.95%、93.52%，RSD分别为1.15%、1.97%。结论 该方法易操作、可靠，可用于龙山卷丹百合中砷、汞含量的测定，同时为龙山卷丹百合生产与育种基地选址提供参考。 　　关键词：卷丹百合；微波消解；原子荧光法；砷；汞 　　DOI：10.3969/j.issn.1005-5304.2018.03.020 　　中图分类号：R284.1 文献标识码：A 文章编号：1005-5304（2018）03-0090-04 　　Abstract： Objective To analyze and discuss the content determination of As and Hg from Lilium Lancifolium in Longshan County； To optimize microwave digestion conditions. Methods Automatic microwave digestion appratus was used. Lilium Lancifolium samples from Longshan County were digested in teflon microwave tube with HNO3-H2O2， and As and Hg were measured with atomic fluorescence spectrometry （AFS）. Results The content of As was in the range of 0.031?C0.507 mg/kg， and the highest content of Hg was 0.024 mg/kg. The regression equation was Y=221.23X+170.72 （r=0.995 9）， Y=503.52X-682.43， （r=0.999 2）. For the production base， the recoveries of As and Hg were 94.32% and 92.48% in the samples， and RSD were 2.14% and 2.70%； for the breeding base， the recoveries of As and Hg were 94.95% and 93.52% in the samples， and RSD were 1.15% and 1.97%. Conclusion The method is simple and reliable， which can be used to the content determination of As and Hg from Lilium Lancifolium， and provide references for the choice of base of production and breeding of Lilium Lancifolium in Longshan County. 　　Keywords： Lilium Lancifolium； microwave digestion； atomic fluorescence spectrometry； As； Hg 　　百合?榘俸峡瓢俸鲜舳嗄晟?草本球根植物，株高一般约70～150 cm，鳞茎为其主要药用部位，先端常开放如莲座状，整体呈淡白色球形，由多片肉质肥厚、卵匙形的鳞片聚合而成，具有养心安神、润肺止咳功效[1-2]。近年来，随着人们对食品药品中重金属问题的高度关注，国内外对中药材的质量要求逐渐提高，从产地环境到饮片，对重金属、硫、农药残留等指标控制十分严格[3-4]。龙山县卷丹百合Lilium lancifolium Thunb.种植基地是我国最大的药用百合种植集中区，也是湖南省龙山县的支柱产业。重金属是否超标已成为影响当地卷丹百合销售的关键性问题