Slide-Set-9-Rheology-Polymer-Melts-课件.ppt

Deborah Number Stress analyses are based upon: Time, Temperature, Rate EMA 4161C - Polymer Physical Properties * Dimensionless number, related directly to the relaxation time or diffusion time of the polymer chains and the experimental time. Critical to consider with respect to the processing design. Reynolds Number A descriptor for the boundary between “laminar” or plug flow and “turbulent” flow. The Re value must exceed 2100 to 2300 to reach turbulent flow character. EMA 4161C - Polymer Physical Properties * Where D is the diameter (cm) of the channel, V is the velocity of the fluid, ? is the density (kg/m3), and ? is the viscosity ( Pa.sec). Velocity is expressed as: Where Q is output (cm3/sec) and A is cross sectional area of channel. Estimation of Re Given the following information, estimate the Re. Diameter of channel = 0.375 cm ? = 175 Pa.sec ? = 980 kg/m3 Q = 275 cm3/sec First solve for V: Q/A where A is: EMA 4161C - Polymer Physical Properties * Then Re: References Introduction to Physical Polymer Science, 4th Edition, Lesley H. Sperling, Wiley Interscience (1992) ISBN 0-471-53035-2 Some figures were reproduced from: Polymer Processing Fundamentals, Tim A. Osswald (1998), Hanser/Gardner Publications, Cincinnati, OH. The Physics of Polymers, Gert Strobl (1996) Springer-Verlag, New York. EMA 4161C - Polymer Physical Properties * Normal Stresses – Die Swell EMA 4161C - Polymer Physical Properties * D1 Do L1 D2 Do L2 Die Swell in Parison Wall thickness is given by: Die Swell in Parison is given by: Thermosets EMA 4161C - Polymer Physical Properties * Cg ~ Gel Point (M ? ? ) C~ degree of cure (consumed functional groups) C1, C2 ~ constants for the data TTr Phase Diagram EMA 4161C - Polymer Physical Properties * * * End class on Sept 30, 2002 EMA 4161C - Polymer Physical Properties EMA 4161C - Polymer Physical Properties EMA 4161C - Polymer Physical Properties EMA 4161C - Polymer Physical Properties EMA 4666C - Polymer Processing Copyright Protected