【毕业论文】碱改性高岭土的性能研究及其应用.docVIP

PAGE 学号： 24082700786 南湖学院 毕业设计 题 目： 碱改性高岭土的性能研究及其应用 作 者 届 别 2012届 系 别 建筑与化学工程系 专 业 制药工程 指导老师 职 称 高级工程师 完成时间 2012.05 湖南理工学院本科毕业论文 摘要 Ⅰ 摘 要 高岭土是制造FCC催化剂的主要基质材料之一。目前，FCC催化剂含有多达50%的原高岭土，这部分高岭土充当惰性载体，基本上不具有裂化反应活性。提高其活性的有效途径有对惰性的高岭土进行酸改性和碱改性。本文主要就不同焙烧温度下的高岭土分别经不同浓度碱液改性后的性能进行研究及其应用，并利用N2吸附法、IR酸性表征、XRD等手段研究了碱改性高岭土基质催化剂的性能特点。结果表明，经碱改性后的高岭土形成了一定活性的中大孔结构并具有一定的酸性中心，并且随着碱液浓度的增大和反应时间的延长，其反应活性不断增强。焙烧高岭土经过酸和碱抽提后，在高岭土中形成了比较通畅的孔道结构，同时，比表面积提高，酸量增加。 关键词：FCC催化剂；高岭土；碱改性；性能；应用 Abstract Kaolin is one of the main matrix materials of the FCC catalyst. Currently, the FCC catalyst contains up to 50% of the original kaolin，acting as inert matrix，which basically has no cracking reaction activity. The effective ways to enhance its activity are alkali-modified and acid-modified on. In this paper, the properties and characterization of the kaolin have mainly been studied. Different concentrations of alkali solution and different calcination temperatures effects on pove volume and acidity center have been studied. Some measures have been to study the modified kaolin catalyst’s performance and application，such as N2 adsorption，IR characterization and XRD. The results showed that the modified kaolin formed the macroporous structure with a certain activity and acidity center，with the increasing of the alkali solution’s concentration and the reaction time，its reactivity is also constantly enhanced. Calcined kaolin by acid and alkali extraction in kaolin, formed a relatively pore structure, at the same time, the specific surface area increase, was increased Key words: FCC catalyst; kaolin; alkali-modification; performance; application 目 录 摘要 …………………………………………………………………………………………Ⅰ Abstract ……………………………………………………………………………………Ⅱ 文献综述 ……………………………………………………………………………1 1.1 引言 ……………………………………………………………………………………1 1.2 FCC催化剂发展现状 ……………………………………………………………………1 1.2.1 国内外裂化催化剂发展现状…………………………………………………1 1.2.2 新世纪催化剂发展方